Hostname: page-component-cd9895bd7-dzt6s Total loading time: 0 Render date: 2024-12-27T22:57:41.890Z Has data issue: false hasContentIssue false
  • English
  • Français

In situ Raman and UV-Vis spectroscopic analysis of lithium-ion batteries

Published online by Cambridge University Press:  22 June 2015

Marcel Heber ,
Christian Schilling ,
Toni Gross  and
Christian Hess
Marcel Heber
Affiliation:
Eduard-Zintl-Institut für Anorganische und Physikalische Chemie, Technische Universität Darmstadt, Alarich-Weiss-Str. 8, 64287 Darmstadt, Germany
Christian Schilling
Affiliation:
Eduard-Zintl-Institut für Anorganische und Physikalische Chemie, Technische Universität Darmstadt, Alarich-Weiss-Str. 8, 64287 Darmstadt, Germany
Toni Gross
Affiliation:
Eduard-Zintl-Institut für Anorganische und Physikalische Chemie, Technische Universität Darmstadt, Alarich-Weiss-Str. 8, 64287 Darmstadt, Germany
Christian Hess
Affiliation:
Eduard-Zintl-Institut für Anorganische und Physikalische Chemie, Technische Universität Darmstadt, Alarich-Weiss-Str. 8, 64287 Darmstadt, Germany
Get access

Abstract

The potential of Raman and UV-Vis diagnostics for spatially-resolved and in situ diagnostics of lithium-ion batteries is demonstrated. Regarding the use of in situ Raman diagnostics focus is put on LiCoO2 electrode materials, which were investigated in detail as composites of LiCoO2 with binder and conductive additives. The potential of in situ UV-Vis analysis is illustrated for carbon-based materials showing significant absorption changes during electrochemical cycling due to lithium de-/intercalation.

Keywords

energy storageintercalationRaman spectroscopy
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1773: Symposium G – Next Generation Electrochemical Energy Storage and Conversion Systems―Synthesis, Processing, Characterization and Manufacturing , 2015 , pp. 33 - 40
Copyright
Copyright © Materials Research Society 2015 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Goodenough, J. B., Acc. Chem. Res. 46, 1053 (2013).CrossRefGoogle Scholar
Hausbrand, R., Cherkashinin, G., Ehrenberg, H., Gröting, M., Albe, K., Hess, C. and Jaegermann, W., Mater. Sci. Eng. B 192, 3 (2015).CrossRefGoogle Scholar
Takamatsu, D., Koyama, Y., Orikasa, Y., Mori, S., Nakatsutsumi, T., Hirano, T., Tanida, H., Arai, H., Uchimoto, Y. and Ogumi, Z., Angew. Chem. Int. Ed. 124, 11765 (2012).CrossRefGoogle Scholar
Yu, L., Liu, H., Wang, Y., Kuwata, N., Osawa, M., Kawamura, J. and Ye, S., Angew. Chem. Int. Ed. 52, 5753 (2013).CrossRefGoogle Scholar
Baddour-Hadjean, R. and Pereira-Ramos, J.-P., Chem. Rev. 110, 1278, (2010).CrossRefGoogle Scholar
Novak, P., Panitz, J. C., Joho, F., Lanz, M., Imhof, R. and Coluccia, M., J. Power Sources 90, 52 (2000).CrossRefGoogle Scholar
Kerlau, M., Marcinek, M., Srinivasan, V. and Kostecki, R., Electrochim. Acta 52, 5422 (2007).CrossRefGoogle Scholar
Gross, T. and Hess, C., J. Power Sources 256, 220 (2014).CrossRefGoogle Scholar
Xie, L. and Lu, J., J. Electroanal. Chem. 497, 159 (2001).CrossRefGoogle Scholar
Herklotz, M., Scheiba, F., Hinterstein, M., Nikolowski, K., Knapp, M., Dippel, A., Giebeler, L., Eckert, J. and Ehrenberg, H., J. Appl. Cryst. 46, 1117 (2013).CrossRefGoogle Scholar
Gross, T., Giebeler, L. and Hess, C., Rev. Sci. Instr. 84, 073109 (2013).CrossRefGoogle Scholar
Gross, T. and Hess, C., ECS Transactions 61, 1 (2014).CrossRefGoogle Scholar
Julien, C., Solid State Ionics 136-137, 887 (2000).CrossRefGoogle Scholar
Membreno, N., Park, K., Goodenough, J. B. and Stevenson, K. J., Chem. Mater. 27, 3332 (2015).CrossRefGoogle Scholar
Itoh, T., Sato, H., Nishina, T., Matue, T. and Ushida, I., J. Power Sources 68, 333 (1997).CrossRefGoogle Scholar
Inaba, M., Iriyama, Y., Ogumi, Z., Todzuk, Y. and Tasaka, A., J. Raman Spectrosc. 28, 613 (1997).3.0.CO;2-T>CrossRefGoogle Scholar
Inaba, M., Yoshida, H., Yida, H., Ogumi, Z., Abe, T., Mizutani, Y. and Asano, M., J. Electrochem. Soc. 142, 20 (1995).CrossRefGoogle Scholar
Novak, P., Joho, F., Imhof, R., Panitz, J.-C. and Haas, O., J. Power Sources 81-81, 212 (1999).CrossRefGoogle Scholar
Hardwick, L. J., Hahn, M., Ruch, P., Holzapfel, M., Scheifele, W., Buqa, H., Krumeich, F., Novak, P. and Kötz, R., Electrochim. Acta 51, 675 (2006).CrossRefGoogle Scholar
Novak, P., Goers, D., Hardwick, L., Holzapfel, M., Scheifele, W., Ufheil, J. and Würsig, A., J. Power Sources 146, 15 (2005).CrossRefGoogle Scholar
Harris, S. J., Timmons, A., Baker, D. R. and Monroe, C., Chem. Phys. Lett. 485, 265 (2010).CrossRefGoogle Scholar
Hardwick, L. J., Buqa, H., Holzapfel, M., Scheifele, W., Krumeich, F. and Novak, P., Electrochim. Acta 52, 4884 (2007).CrossRefGoogle Scholar
Sole, C., Drewett, N. E. and Hardwick, L. J., Faraday Disc. 172, 223 (2014).CrossRefGoogle Scholar