Hostname: page-component-78c5997874-4rdpn Total loading time: 0 Render date: 2024-11-10T06:02:23.713Z Has data issue: false hasContentIssue false

Influence of the Particle Morphology on the Micro-and Macromechanics of Nano-Reinforced Materials

Published online by Cambridge University Press:  01 February 2011

Alexander Sarkissov
Affiliation:
Eindhoven University of Technology, P.O.B. 513, 5600 MB, Eindhoven, The Netherlands.
Han Meijer
Affiliation:
Eindhoven University of Technology, P.O.B. 513, 5600 MB, Eindhoven, The Netherlands.
Hartmut Fischer
Affiliation:
Innovative Materials, TNO TPD, P.O.B. 595, 5600 AN Eindhoven, The Netherlands and TU Delft, Aerospace Engineering, Kluyverweg 1, 2629 HS Delft, The Netherlands
Get access

Abstract

This paper describes mechanical properties of polymer-clay nanocomposites with platelet and fibrous like nanoparticles evaluated on a of nano, meso and micro length scale. Platelet reinforced materials were found to display a mixed morphology consisting of intercalated and exfoliated regions. A better dispersion was obtained for fibrous clay nanocomposites where homogeneous distribution of single particles was achieved. The deformation behavior was investigated by in-situ XRD and SEM experiments during drawing; the macro-mechanical characteristics were extracted from tensile tests. The stiffness was found to increase in both platelet and fibrous clay nanocomposites. The presence of intercalated stacks in the latter resulted in a significant reduction in drawability, the better homogeneity of the fibrous clay systems allowed a reasonably high extensions.

Type
Research Article
Copyright
Copyright © Materials Research Society 2005

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Dubois, P., P., , Alexandre, M., Mat. Sci. Eng., 28, 1 (2000)Google Scholar
2. Park, J. H., Jana, S. C., Macromolecules, 36, 2758 (2003)Google Scholar
3. Mitsunaga, M., Ito, Y., Ray, S. S., Okamoto, M., Hironaka, K., Macromol. Mat. Eng., 288, 543 (2003)Google Scholar
4. Grim, R. E., Clay Mineralogy, (McGraw-Hill Book Company 1968) p. 77, 113Google Scholar
5. Theng, B.K.G., Formation of Polymer-Clay Complexes, Development in soil science 9, Elsevier, (1979) p.1022 Google Scholar
6. Acosta, J., Rocha, C., Ojeda, M., Linares, A., Arroyo, M., Ang. Makromol. Chem. 126, 51 (1984), Ang. Makromol. Chem. 139, 201 (1986),Google Scholar
Linares, A., Morales, E., Ojeda, M., Acosta, J., Ang. Makromol. Chem. 147, 41 (1987)Google Scholar
Acosta, J., Ojeda, M., Morales, E., Linares, A., J. Appl. Polym. Sci., 31, 2351 (1986), J. Appl. Polym. Sci., 32, 4119 (1986)Google Scholar
7. Rong, J., Jing, Z., Li, H., Sheng, M., Macromol. Rapid Com., 22, 329 (2001)Google Scholar
8. Sarkissov, A., Fischer, H., Meijer, H.E.H., On The Preparation of Inorganic-Organic Nanocomposites from Fibrous Minerals and Polymers –in preparationGoogle Scholar
9. Shahin, M., Olley, R., Blissett, M., J. Polym. Sci. Polym. Phys., 37, 2279 (1999)Google Scholar