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In-situ X-ray Studies of Clean Catalytic Technologies

Published online by Cambridge University Press:  25 July 2011

Adam F. Lee ,
Christine V. Ellis ,
Mark A. Newton ,
Christopher M. Parlett  and
Karen Wilson
Adam F. Lee
Affiliation:
Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Cardiff, United Kingdom;
Christine V. Ellis
Affiliation:
Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Cardiff, United Kingdom;
Mark A. Newton
Affiliation:
Electronic Structure and Magnetism, European Synchrotron Radiation Facility, Grenoble, France
Christopher M. Parlett
Affiliation:
Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Cardiff, United Kingdom;
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Abstract

The rational design of new heterogeneous catalysts for clean chemical technologies can be accelerated by molecular level insight into surface chemical processes. In-situ methodologies, able to provide time-resolved and/or pressure dependent information on the evolution of reacting adsorbed layers over catalytically relevant surfaces, are therefore of especial interest. Here we discuss the application of in-situ XPS and in-situ, synchronous DRIFTS/MS/XAS methodologies to elucidate the active site in Pd-catalyzed, selective aerobic oxidation of allylic alcohols.

Keywords

Pdoxidationextended x-ray absorption fine structure(EXAFS)
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1351: Symposium FF – Surfaces and Nanomaterials for Catalysis through In-Situ or Ex-Situ Studies , 2011 , mrss11-1351-ff16-05
Copyright
Copyright © Materials Research Society 2011

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References

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