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Lithium-Iodine Intercalation in The Ferroelectric Layered Compound Bi4Ti3O12-x

Published online by Cambridge University Press:  16 February 2011

T. Kijima ,
S. Kimura ,
Y. Kawahara ,
K. Ohe ,
M. Yada  and
M. Machida
T. Kijima
Affiliation:
Department of Materials Science, Faculty of Engineering, Miyazaki University, Miyazaki 889-21, Japan
S. Kimura
Affiliation:
Department of Materials Science, Faculty of Engineering, Miyazaki University, Miyazaki 889-21, Japan
Y. Kawahara
Affiliation:
Department of Materials Science, Faculty of Engineering, Miyazaki University, Miyazaki 889-21, Japan
K. Ohe
Affiliation:
Department of Materials Science, Faculty of Engineering, Miyazaki University, Miyazaki 889-21, Japan
M. Yada
Affiliation:
Department of Materials Science, Faculty of Engineering, Miyazaki University, Miyazaki 889-21, Japan
M. Machida
Affiliation:
Department of Materials Science, Faculty of Engineering, Miyazaki University, Miyazaki 889-21, Japan
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Abstract

The reaction of Bi4Ti3O12-x with lithium iodide under an atmosphere of iodine at 400°C was found to afford a novel intercalation compound Lil3Bi4Ti3O11. The brownish red bismuth titanate is monoclinic with the lattice parameters of a=5.7417(2), b=5.4016(2), c=36.787(1) Å and ß=88.93(1) deg. The pathway to the new intercalation compound is proposed on the basis of X-ray, XPS, SEM and compositional observations.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 547: Symposium DD – Solid-State Chemistry of Inorganic Materials II , 1998 , 151
Copyright
Copyright © Materials Research Society 1999

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