Published online by Cambridge University Press: 22 February 2011
Low temperature, 600°C annealing of LPCVD films was investigated by x-ray diffraction, ESR, TEM, and carrier mobility measurements. An optimum deposition temperature of about 550°C was found to yield good crystallinity and large electron mobility for annealed films; large grain sizes, a maximum crystallite size, and a maximum electron spin density were also observed for films deposited at the optimum temperature. Electron spin density for as-deposited films correlated with the crystalline volume by x-ray diffraction measurements on the films after annealing. This implys that only those amorphous components with high electron spin density can be converted into the crystalline phase by 600°C annealing.