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Macroscopic and Microscopic Aspects of Electron Hopping in Mixed Conductor Membranes using the Quasi-Fermi level

Published online by Cambridge University Press:  21 February 2011

Richard P. Buck
Richard P. Buck*
Affiliation:
Dept. of Chemistry, University of North Carolina, Chapel Hill, NC 27599-3290
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Abstract

Electron transport in mixed conductor redox electrolyte membranes: anion/electron charge carriers, and cation/electron charge carriers are analyzed by irreversible thermodynamic methods appropriate to electrolyte transport. The generalized force for electron transport is the gradient of the Fermi level of electrons in electrolyte phases. The generalized force for ion transport is the gradient of the ionic electrochemical potential. New results include current-time, current-voltage, small amplitude and DC bias impedance functions.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 135: Symposium M – Solid State Ionics I , 1988 , 83
Copyright
Copyright © Materials Research Society 1989

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References

1. Buck, R. P., J. Electroanal. Chem., 243, 279–292 (1988).Google Scholar
2. Buck, R. P., J. Phys. Chem., 92, 4196 (1988).Google Scholar
3. Buck, R. P., J. Phys. Chem., “Comparison of Steady State Electrical Properties For Two Counterion and Electron-Counterion Membranes”, J. Phys. Chem. (in press, 1988).Google Scholar
4. Buck, R. P., “Time-dependent, Coupled Electron Hopping-Anion Displacement in Fixed-Site Polymer Membranes”, J. Electroanal. Chem., (in press, September 1988).Google Scholar
5. Levich, V. G., in Advances in Electrochemistry and Electrochemical Engineering, Interscience: New York; Vol. 4, pp 314–315.Google Scholar
6. Wahl, A. C. and Bonner, N.A., Radioactivity Applied to Chemistry, Wiley, New York, 1951, Chapter 1.Google Scholar
7. Saveant, J. M., J. Electroanal. Chem., 201, 211 (1986).Google Scholar
8. Chapman, T. W. and Newman, J., J. Phys. Chem., 71, 241–245 (1967).Google Scholar
9. Buck, R. P., J. Electroanal. Chem., 210, 1–19 (1986).Google Scholar
10. Buck, R. P., J. Electroanal. Chem., 219, 23–48 (1987).Google Scholar