Hostname: page-component-745bb68f8f-mzp66 Total loading time: 0 Render date: 2025-01-15T07:06:45.969Z Has data issue: false hasContentIssue false
  • English
  • Français

Molecule Derived Nanomaterials: Chemical Concepts for Composition, Morphology and Particle Size Control

Published online by Cambridge University Press:  01 February 2011

Sanjay Mathur
Sanjay Mathur*
Affiliation:
Institute of New MaterialsD-66041 Saarbruecken, Germany
Get access

Abstract

Conventional material synthesis procedures rely on the intrinsic chemical behaviours (e.g., different hydrolysis rates of the reactants in solution phase reactions or different vapour pressure or thermal stability in the gas phase reactions) of the different components, which make the material properties susceptible to inaccuracies due to an increased number of process variables. As a consequence, phase separation and element segregation are present at the nanometer scale, although the global stoichiometry of the product may correspond to the desired composition. In this context, the use of well-defined molecular precursors is a promising approach to grow extended solid-state structures from atomic constituents.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 788: Symposium L – Continuous Nanophase and Nanostructured Materials , 2003 , L1.6
Copyright
Copyright © Materials Research Society 2004

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Edelstein, A. S., and Cammarata, R. C., eds. Nanomaterials: Synthesis, properties and applications, Institute of Physics Publishers, Bristol and Philadelphia (1996).Google Scholar
2. (a) Veith, M. Dalton Trans. 2405 (2002).Google Scholar
(b) Jones, A. C. Chem. Soc. Rev. 101 (1997).Google Scholar
3. Mathur, S., in NATO ASI Series: Chemical Physics of Thin Film Deposition for Micro- and Nano-Technologies ed. Pauleau, Y., Kluwer Academic Publications (2002) p. 91.Google Scholar
4. Veith, M., Mathur, S., Huch, V. and Decker, T. Eur. J. Inorg. Chem. 1327 (1998).Google Scholar
5. Deb, K. K., Hill, M. D. and Kelly, J. F. J. Mater. Res. 7, 3296 (1992).Google Scholar
6. Veith, M., Mathur, S., Lecerf, N., Huch, V., Decker, T., Beck, H. P., Eiser, W., Haberkorn, R. J. Sol-Gel Sci. Tech. 17, 145 (2000).Google Scholar
7. Mathur, S., Shen, H., Lecerf, N., Kjekshus, A., Fjellvåg, H., and Goya, G. F. Adv. Mater. 14, 1405 (2002).Google Scholar
8. Schmool, D. S., Keller, N., Guyot, M., Krishnan, R. and Tessier, M. J. Magn. Magn. Mater. 195, 291 (1999).Google Scholar
9. Mathur, S., Veith, M., Sivakov, V., Shen, H., Huch, V., Hartmann, U., and Gao, H. B., Chem. Vapor Deposition, 8, 277 (2002).Google Scholar
10. Mathur, S. and Shen, H. in Encyclopedia of Nanoscience and Nanotechnology ed. Nalwa, H. S., American Scientific Publishers (2003).Google Scholar