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Nanocrystalline Doped Ceria-Zirconia Fluorite-Like Solid Solutions Promoted by Pt: Structure, Surface Properties and Catalytic Performance in Syngas Generation

Published online by Cambridge University Press:  26 February 2011

Vladislav A Sadykov ,
Natalia Mezentseva ,
Galina Alikina ,
Anton Lukashevich ,
Vitalii Muzykantov ,
Tatiana Kuznetsova ,
Lubsan Batuev ,
Martin Fedotov ,
Ella Moroz  and
Dmitrii Zyuzin
...Show all authors
Vladislav A Sadykov
Affiliation:
sadykov@catalysis.ru, Boreskov Institute of Catalysis, Heterogeneous catalysis, pr. Lavrentieva, 5, Novosibirsk, 630090, Russian Federation, +7-383-330-8763, +7-383-330-80-56
Natalia Mezentseva
Affiliation:
mnv@catalysis.ru, Boreskov Institute of Catalysis, Heterogeneous catalysis, pr. Lavrentieva, 5, Novosibirsk, 630090, Russian Federation
Galina Alikina
Affiliation:
galikina@yandex.ru, Boreskov Institute of Catalysis, Heterogeneous catalysis, pr. Lavrentieva, 5, Novosibirsk, 630090, Russian Federation
Anton Lukashevich
Affiliation:
toshik@yandex.ru, Boreskov Institute of Catalysis, Heterogeneous catalysis, pr. Lavrentieva, 5, Novosibirsk, 630090, Russian Federation
Vitalii Muzykantov
Affiliation:
muzykantov@catalysis.ru, Boreskov Institute of Catalysis, Heterogeneous catalysis, pr. Lavrentieva, 5, Novosibirsk, 630090, Russian Federation
Tatiana Kuznetsova
Affiliation:
tgkuzn@catalysis.ru, Boreskov Institute of Catalysis, Heterogeneous catalysis, pr. Lavrentieva, 5, Novosibirsk, 630090, Russian Federation
Lubsan Batuev
Affiliation:
tgkuzn@catalysis.ru, Boreskov Institute of Catalysis, Heterogeneous catalysis, pr. Lavrentieva, 5, Novosibirsk, 630090, Russian Federation
Martin Fedotov
Affiliation:
nmrmartin@mail.ru, Boreskov Institute of Catalysis, Heterogeneous catalysis, pr. Lavrentieva, 5, Novosibirsk, 630090, Russian Federation
Ella Moroz
Affiliation:
emoroz@catalysis.ru, Boreskov Institute of Catalysis, Heterogeneous catalysis, pr. Lavrentieva, 5, Novosibirsk, 630090, Russian Federation
Dmitrii Zyuzin
Affiliation:
zyuzin@catalysis.ru, Boreskov Institute of Catalysis, Heterogeneous catalysis, pr. Lavrentieva, 5, Novosibirsk, 630090, Russian Federation
Vera Kolko
Affiliation:
emoroz@catalysis.ru, Boreskov Institute of Catalysis, Heterogeneous catalysis, pr. Lavrentieva, 5, Novosibirsk, 630090, Russian Federation
Vladimir Kriventsov
Affiliation:
kriven@mail.ru, Boreskov Institute of Catalysis, Heterogeneous catalysis, pr. Lavrentieva, 5, Novosibirsk, 630090, Russian Federation
Vyacheslav Ivanov
Affiliation:
vpivanov@catalysis.ru, Boreskov Institute of Catalysis, Heterogeneous catalysis, pr. Lavrentieva, 5, Novosibirsk, 630090, Russian Federation
Andrei Boronin
Affiliation:
boronin@catalysis.ru, Boreskov Institute of Catalysis, Heterogeneous catalysis, pr. Lavrentieva, 5, Novosibirsk, 630090, Russian Federation
Egor Pazhetnov
Affiliation:
gosha@catalysis.ru, Boreskov Institute of Catalysis, Heterogeneous catalysis, pr. Lavrentieva, 5, Novosibirsk, 630090, Russian Federation
Vladimir Zaikovskii
Affiliation:
viz@catalysis.ru, Boreskov Institute of Catalysis, Heterogeneous catalysis, pr. Lavrentieva, 5, Novosibirsk, 630090, Russian Federation
Arcady Ishchenko
Affiliation:
viz@catalysis.ru, Boreskov Institute of Catalysis, Heterogeneous catalysis, pr. Lavrentieva, 5, Novosibirsk, 630090, Russian Federation
Vladimir Rogov
Affiliation:
rogov@catalysis.ru, Boreskov Institute of Catalysis, Heterogeneous catalysis, pr. Lavrentieva, 5, Novosibirsk, 630090, Russian Federation
Julian Ross
Affiliation:
Julian.Ross@ul.ie, University of Limerick, Limerick, N/A, Ireland
Erhard Kemnitz
Affiliation:
Erhard.Kemnitz@chemie.hu-berlin.de, Humboldt University, Berlin, D-12489, Germany
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Abstract

Nanocrystalline ceria-zirconia samples doped with rare-earth (Gd, Pr, Sm, La) cations were prepared via modified Pechini route. Effect of their real structure and surface composition characterized by a combination of sophisticated physical methods (XRD, TEM +EDX, EXAFS, WAXS, UV-Vis, XPS, SIMS) on the mobility and reactivity of the lattice oxygen estimated by oxygen isotope exchange, H2, CH4 and CO TPR was analyzed. For the reaction of acetone autothermal reforming into syngas, catalytic activity correlates rather well with the oxygen mobility controlled by the type and content of a dopant

Keywords

catalyticCenanostructure
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 988: Symposium QQ – Solid-State Chemistry of Inorganic Materials VI , 2006 , 0988-QQ06-04
Copyright
Copyright © Materials Research Society 2007

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References

1. Kašpar, J., Fornasiero, P., in: Catalysis by Ceria and Related Materials; (A., Trovarelli, Ed.), Catalytic Science Series, V.2, pp. 217–241, Imperial College Press, London, UK (2002)Google Scholar
2. Sadykov, V. A., Kuznetsova, T. G., Frolova, Yu. V., Alikina, G. M., Lukashevich, A. I., et al, Catal. Today 117, 475 (2006)Google Scholar
3. Mogensen, M., Sammes, N. M., Tompsett, G. A., Solid State Ionics 129, 63 (2000).Google Scholar
4. Takanabe, K., Aika, K., Seshan, K., Lefferts, L., J. Catal. 227, 101 (2004).Google Scholar
5. Sadykov, V. A., Frolova- Borchert, Yu. V., Mezentseva, N. V., Alikina, G. M., Lukashevich, A. I., Muzykantov, V. S. et al, Mater. Res. Soc. Symp. Proc. 900E, O10.04 (2006)Google Scholar
6. Kochubey, D. I., EXAFS spectroscopy of catalysts, Nauka, Novosibirsk, 1992 Google Scholar
7. Mamontov, E., Brezny, R., Koranne, M., Egami, T., J. Phys. Chem. B. 107, 13007 (2003).Google Scholar
8. Sadykov, V., Voronin, V., Petrov, A., Frolova, Yu., Kriventsov, V., Kochubei, D., Zaikovskii, V., Borchert, H., Mater. Res. Soc. Symp. Proc. 835, 205 (2005)Google Scholar
9. Shannon, R. D., Acta Crystallogr. Sec. A 32, 751 (1976)Google Scholar
10. Borchert, H., Borchert, Yu., Kaichev, V. V., et al, J. Phys. Chem. B. 109, 5728 (2005).Google Scholar