Hostname: page-component-78c5997874-v9fdk Total loading time: 0 Render date: 2024-11-10T08:35:58.540Z Has data issue: false hasContentIssue false
  • English
  • Français

New Copolymers Based on Acenaphto[1,2-b]thieno[3,4-e]Pyrazine for Transistor and Solar Cell Applications

Published online by Cambridge University Press:  31 January 2011

Pierre-Luc T. Boudreault ,
Nobuyuki Miyaki ,
Rajib Mondal ,
Ming Lee Tang ,
Zhenan Bao  and
Mario Leclerc
Pierre-Luc T. Boudreault
Affiliation:
pierre-luc.boudreault.1@ulaval.ca, Université Laval, Chemistry, Québec City, Canada
Nobuyuki Miyaki
Affiliation:
nmiyaki@stanford.edu, Stanford University, Chemical Engineering, Stanford, California, United States
Rajib Mondal
Affiliation:
rmondal@stanford.edu, Stanford University, Chemical Engineering, Stanford, California, United States
Ming Lee Tang
Affiliation:
mltang@stanford.edu, Stanford University, Chemical Engineering, Stanford, California, United States
Zhenan Bao
Affiliation:
zbao@stanford.edu, Stanford University, Chemical Engineering, Stanford, California, United States
Mario Leclerc
Affiliation:
mario.leclerc@chm.ulaval.ca, Université Laval, Chemistry, Québec City, Canada
Get access

Abstract

We will show the synthesis of new donor-acceptor copolymers based on 2,7-carbazole or 2,7-dibenzosilole and acenaphtho[1,2-b]thieno[3,4-e]pyrazine. After the synthesis of these new copolymers, we have characterized the materials by UV-vis, DSC, and XRD to determine the degree of organization. Afterward, we have fabricated and investigated field-effect transistors and photovoltaic cells from these polymers. The optimization of the thin film by thermal treatment have led to a field-effect mobility of 0.04 cm2/(V.s) and power conversion efficiency of 0.44%.

Keywords

polymerphotovoltaicoptoelectronic
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1197: Symposium D – Organic Materials for Printable Thin-Film Electronic Devices , 2009 , 1197-D02-05
Copyright
Copyright © Materials Research Society 2010

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

[1] Svensson, M., Zhang, F., Veenstra, S. C., Verhees, W. J. H., Hummelen, J. C., Kroon, J. M., Inganäs, O., Andersson, M. R., Adv. Mater. 2003, 15, 988.Google Scholar
[2] Zhang, F., Mammo, W., Andersson, L. M., Admassie, S., Andersson, M. R., Inganäs, O., Adv. Mater. 2006, 18, 2169.Google Scholar
[3] Peet, J., Kim, J. Y., Coates, N. E., Ma, W. L., Moses, D., Heeger, A. J., Bazan, G. C., Nat. Mater. 2007, 6, 497.Google Scholar
[4] Blouin, N., Michaud, A., Gendron, D., Wakim, S., Blair, E., R. Neagu-Plesu, Belletete, M., Durocher, G., Tao, Y., Leclerc, M., J. Am. Chem. Soc. 2008, 130, 732.Google Scholar
[5] Boudreault, P.-L. T., Michaud, A., Leclerc, M., Macromol. Rapid Commun. 2007, 28, 2176.Google Scholar
[6] Wang, E., Wang, L., Lan, L., Luo, C., Zhuang, W., Peng, J., Cao, Y., Appl. Phys. Lett. 2008, 92, 033307.Google Scholar
[7] Hou, J., Chen, H.-Y., Zhang, S., Li, G., Yang, Y., J. Amer. Chem. Soc. 2008, 130, 16144.Google Scholar
[8] Hou, J., Chen, H.-Y., Zhang, S., Chen, R. I., Yang, Y., Wu, Y., Li, G., J. Amer. Chem. Soc. 2009, 131, 15586.Google Scholar
[9] Mammo, W., Admassie, S., Gadisa, A., Zhang, F., Inganäs, O., Andersson, M. R., Solar Energy Mater. Solar Cells 2007, 91, 1010.Google Scholar
[10] Becerril, H. A., Miyaki, N., Tang, M. L., Mondal, R., Sun, Y.-S., Mayer, A. C., Parmer, J. E., McGehee, M. D., Bao, Z., J. Mater. Chem. 2009, 19, 591.Google Scholar
[11] Boudreault, P.-L. T., Blouin, N., Leclerc, M., Adv. Polym. Sci. 2008, 212, 99.Google Scholar
[12] Wong, W., Holmes, A. B., Adv. Polym. Sci. 2008, 212, 85.Google Scholar
[13] Chan, K. L., McKiernan, M. J., Towns, C. R., Holmes, A. B., J. Am. Chem. Soc. 2005, 127, 7662.Google Scholar
[14] Blouin, N., Michaud, A., Leclerc, M., Adv. Mater. 2007, 19, 2295.Google Scholar
[15] Zhang, M., Tsao, H. N., Pisula, W., Yang, C., Mishra, A. K., Mullen, K., J. Am. Chem. Soc. 2007, 129, 3472.Google Scholar
[16] Mühlbacher, D., Scharber, M., Morana, M., Zhu, Z., Waller, D., Gaudiana, R., Brabec, C., Adv. Mater. 2006, 18, 2884.Google Scholar
[17] Scharber, M. C., Mühlbacher, D., Koppe, M., Denk, P., Waldauf, C., Heeger, A. J., Brabec, C. J., Adv. Mater. 2006, 18, 789.Google Scholar
[18] McCulloch, I., Heeney, M., Bailey, C., Genevicius, K., Macdonald, I., Shkunov, M., Sparrowe, D., Tierney, S., Wagner, R., Zhang, S. W., Chabinyc, M. L., Kline, R. J., McGehee, M. D., Toney, M. F., Nat. Mater. 2006, 5, 328.Google Scholar
[19] DeLongchamp, D. M., Kline, R. J., Lin, E. K., Fischer, D. A., Richter, L. J., Lucas, L. A., Heeney, M., McCulloch, I., Northrup, J. E., Adv. Mater. 2007, 19, 833.Google Scholar