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Nonlinear Optical Materials Synthesized by Ion Implantation: Metal Quantum Dots in Transparent Dielectrics

Published online by Cambridge University Press:  22 February 2011

Richard F. Haglund Jr. ,
D. H. Osborne Jr. ,
LI Yang ,
R. H. Magruder III ,
C. W. White  and
R. A. Zuhr
Richard F. Haglund Jr.
Affiliation:
Department of Physics and Astronomy, Vanderbilt University, Nashville, TN 37235
D. H. Osborne Jr.
Affiliation:
Department of Physics and Astronomy, Vanderbilt University, Nashville, TN 37235
LI Yang
Affiliation:
Department of Physics and Astronomy, Vanderbilt University, Nashville, TN 37235
R. H. Magruder III
Affiliation:
Department of Applied and Engineering Sciences, Vanderbilt University, Nashville, TN 37235
C. W. White
Affiliation:
Solid-State Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831
R. A. Zuhr
Affiliation:
Solid-State Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831
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Abstract

Composites consisting of nanometer-size metal clusters embedded in a host dielectric can be synthesized by implanting metal ions in either glassy or crystalline substrates. The size and size distributions of the nanoclusters can be controlled by varying the parameters either of the ion-implantation process or subsequent annealing. The nonlinear optical response of these quantum-dot composites can be modeled as that of independent electrons confined to a spherical potential well; experimental data on relaxation times compares favorably with this simple picture. Optical figures-of-merit of these materials suggest potential for applications in nonlinear waveguide devices, particularly since ion implantation is compatible with device-fabrication processes. The basic features of these materials are illustrated from experiments on Cu and Pb clusters in silica.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 316: Symposium A – Materials Synthesis and Processing Using Ion Beams , 1993 , 421
Copyright
Copyright © Materials Research Society 1994

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References

REFERENCES

1 Flytzanis, C., Hache, F., Klein, M. C., Ricard, D. and Roussignol, Ph., Prog. Opt. 29, 321 (1991).Google Scholar
2 Haglund, R. F. Jr., Yang, L., Magruder, R. H. III, Wittig, J. E., Becker, K. and Zuhr, R. A., Opt. Lett. 18, 373 (1993).Google Scholar
3 Magruder, R. H. III, Haglund, R. F. Jr., Yang, Li, White, C. W., Yang, Lina, Dorsinville, R. and Alfano, R. R., Appl. Phys. Lett. 62, 465 (1993).Google Scholar
4 White, C. W., Thomas, D. K., Hensley, D. K., Zuhr, R. A., McCallum, J. C., Pogany, A., Haglund, R. F. Jr., Magruder, R. H. and Yang, L., J. Nanostr. Materials, in press (1993).Google Scholar
5 Bloemer, M. J., Haus, J. W. and Ashley, P. R., J. Opt. Soc. Am. B 7, 790 (1990).Google Scholar
6 Hache, F., Ricard, D., Flytzanis, C. and Kreibig, U., Appl. Phys. A 47, 347 (1988).Google Scholar
7 Haus, J. W., Kalyaniwalla, N., Inguva, R., Bloemer, M. and Bowden, C. M., J. Opt. Soc. Am. B 6, 797 (1989).Google Scholar
8 Magruder, R. H. III, Haglund, R. F. Jr., Yang, L., Becker, K. and Zuhr, R. A., Mat. Res. Soc. Symp. Proc. 243, 369 (1992).Google Scholar
9 See Flytzanis, C. and Ouder, J. L., eds., Nonlinear Optics: Materials and Devices, (Heidelberg: Springer-Verlag, 1986.Google Scholar
10 Kittel, C., Introduction to Solid State Physics, 6th Edition (New York: John Wiley, 1986).Google Scholar
11 Faraday, M., Philos. Trans. 147, 145 (1857).Google Scholar
12 For reviews, see Bohren, C. F. and Huffman, D. R., Absorption and Scattering of Light by Small Particles (New York: John Wiley and Sons, 1983), especially Chapters 5 and 12. See also Genzel, L., Martin, T. P. and Kreibig, U., Physik, Z. B 21, 339 (1975).Google Scholar
13 Mie, G., Ann. Phys. 25, 377 (1908).Google Scholar
14 Maxwell-Gamett, C., Phil. Trans. R. Soc. 203, 385 (1904) and ibid., 205 , 237 (1906).Google Scholar
15 Doyle, W. J., Phys. Rev. 111, 1067 (1958). R. H. Doremus, J. Chem. Phys. 40, 2389 (1964) and J. Chem. Phys. 42, 414 (1965). U. Kreibig and L. Genzel, Surf. Sci. 156, 678 (1985).Google Scholar
16 Magruder, R. H. III, Haglund, R. F. Jr., Yang, Li and Zuhr, R. A., submitted to J. Appl. Phys., 1993.Google Scholar
17 Halperin, W. P., Rev. Mod. Phys. 58, 533 (1986).Google Scholar
18 Sheik-Bahae, M., Said, A. A., Wei, T., Hagan, D. J. and VanStryland, E. W., IEEE J. Quant. Elect. 26, 760 (1990).Google Scholar
19 Yang, Li, “Nonlinear Optics of Noble-Metal Crystallites Embedded in Fused Silica Glass,” Ph.D. Dissertation, Vanderbilt University, 1993, unpublished.Google Scholar
20 Ref. 2 and Yang, L., Becker, K., Smith, F. M., Magruder, R. H. III, Haglund, R. F. Jr., Yang, Lina, Dorsinville, R. and Alfano, R. R., J. Opt. Soc. Am. B, in press (Feb. 1994).Google Scholar
21 Ref. 1. and Becker, K., Yang, Li and Haglund, R. F. Jr., submitted to J. Opt. Soc. Am. B. Google Scholar
22 See Saleh, B. E. A. and Teich, M. C., Fundamentals of Photonics (New York: John Wiley and Sons, 1991), Chs. 19, 21, 22.Google Scholar
23 Hall, Dennis G., Prog. Opt. 29,1 (1991).Google Scholar
24 Tamir, T., ed., Guided-Wave Optoelectronics (Heidelberg, Springer-Verlag, 1988).Google Scholar
25 Examples of specific circuits include Jensen, S. M., IEEE J. Quantum. Electron. QE-18, 1580–1583 (1982), and A. Lattes, H. A. Haus, F. J. Leonberger and E. P. Ippen, IEEE J. Quantum Electron. QE-19,1718–1723 (1983).Google Scholar
26 Stegeman, G. I., Wright, E. M., Finlayson, N., Zanoni, R. and Seaton, C. T., IEEE J. Lightwave Tech. 6, 953–970 (1988); G.I. Stegeman and R. H. Stolen, J. Opt. Soc. Am. B 6, 652–662 (1989).Google Scholar
27 See Smith, P. E. W., “All-optical devices: materials requirements,” Proc. SPIE 1852, 2–9 (1993).Google Scholar
28 Yariv, A., Quantum Electronics, Fourth Edition (New York: John Wiley and Son, 1989).Google Scholar
29 Mizrahi, V., DeLong, K. W., Stegeman, G. I., Saifi, M. A. and Andrejco, M. J., Opt. Lett. 14, 1140 (1989). Also G. I. Stegeman, “Material Figures of Merit,” Proc. SPIE 1852, 75.Google Scholar
30 Chandler, P. J., Field, S. J., Hanna, D. C., Shepherd, D. P., Townsend, P. D., Trapper, A. C. and Zhang, L., Elect. Lett. 25 (1989) 985. See also Chandler, P. J., Zhang, L. and P. D.Google Scholar