Hostname: page-component-cd9895bd7-hc48f Total loading time: 0 Render date: 2024-12-29T13:35:56.040Z Has data issue: false hasContentIssue false

Nonvolatile Memory Characteristics of Nanocrystalline Molybdenum Oxide Embedded High-k Film - Device Performance and Light Wavelength Effects

Published online by Cambridge University Press:  25 May 2012

Yue Kuo
Affiliation:
Thin Film Nano & Microelectronics Research Laboratory, Texas A&M University, College Station, TX 77843-3122, U.S.A.
Xi Liu
Affiliation:
Thin Film Nano & Microelectronics Research Laboratory, Texas A&M University, College Station, TX 77843-3122, U.S.A. Department Department of Industrial and Systems Engineering, Ohio University, Athens, OH 45701
Chia-Han Yang
Affiliation:
Thin Film Nano & Microelectronics Research Laboratory, Texas A&M University, College Station, TX 77843-3122, U.S.A. Department of Industrial and Information Engineering, University of Tennessee, Knoxville, TN 37996, U.S.A.
Chi-Chou Lin
Affiliation:
Thin Film Nano & Microelectronics Research Laboratory, Texas A&M University, College Station, TX 77843-3122, U.S.A.
Get access

Abstract

The nanocrystalline molybdenum oxide embedded Zr-doped HfO2 high-k nonvolatile memory device has been fabricated using the one pumpdown sputtering process and a rapid thermal annealing step. The majority embedded molybdenum existed in the MoO3 nanocrystal form but a small amount of metallic molybdenum was also detected. The memory function of this device was based on the hole trapping-and-detrapping mechanism. The embedded nanocrystals retained charges after the breakdown of the high-k stack. The charge storage capacity was influenced by light exposure, especially the wavelength. The silicon/high-k interface was also affected by the exposed light. This study provided an insight of the function of the embedded nanocrystals and the light effects on the device.

Type
Articles
Copyright
Copyright © Materials Research Society 2012

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Chatterjee, S., Samanta, S. K., Banerjee, H. D. and Maiti, C. K., in Semicond. Sci. Technol., vol. 17, p. 993, 2003.Google Scholar
2. Kuo, Y., in ECS Trans., vol. 35, no. 3, p. 13, 2011.Google Scholar
3. Lu, J., Kuo, Y., Yan, J., and Lin, C.-H., in Jpn. J. Appl. Phys., vol. 45, p. L901, 2006.Google Scholar
4. Kuo, Y., Lu, J., Chatterjee, S., Yan, J., Yuan, T., Kim, H.- C., Luo, W., Peterson, J. and Gardner, M., in ECS Trans, vol. 1, no. 5, p. 447, 2006.Google Scholar
5. Triyoso, D. H., in ECS Trans., vol. 3, no. 3, p. 463, 2006.Google Scholar
6. Kuo, Y., in ECS Trans., vol. 3, no. 3, p. 253, 2006.Google Scholar
7. Kuo, Y., in ECS Trans., vol. 2, no. 1, p. 13, 2006.Google Scholar
8. Lu, J., Lin, C.-H. and Kuo, Y., in JES, vol. 115, no. 6, p. H386, 2008.Google Scholar
9. Birge, A. and Kuo, Y., in JES, vol. 154, no. 10, p. H887, 2007.Google Scholar
10. Lin, C.-H. and Kuo, Y., in J. Appl.Phys., vol. 110, 024101, 2011.Google Scholar
11. Yang, C.-H., Kuo, Y., and Lin, C.-H., in Appl. Phys. Letts., vol. 96, p. 192106, 2010.Google Scholar
12. Luo, B., Lin, C.-H., and Kuo, Y., in ECS Trans., vol. 41 no. 3, p. 93, 2011.Google Scholar
13. Hauser, J. and Ahmed, K., Characterization and Metrology for ULSI Technology, p. 235, AIP, New York, 1998.Google Scholar
14. Luo, W., Kuo, Y., and Kuo, W., in IEEE Trans. Device Mater. Rel., vol. 4, p. 488, 2004.Google Scholar
15. Lin, C.-H. and Kuo, Y., in ECS Trans., vol. 35, no. 2, p. 249, 2011.Google Scholar
16. Tiwari, S., Rana, F., Hanafi, H., Hartstein, A., Crabbé, E. F., and Chan, K., in Appl. Phys. Lett., vol. 68, no. 10, p. 1377, 1996.Google Scholar
17. Yang, C.-H., Kuo, Y., Lin, C.-H., and Kuo, W., in ECS Trans., vol. 25, no. 6, p. 457, 2009.Google Scholar
18. Lin, C.-H. and Kuo, Y., in J. Electrochem. Soc., vol. 159, no. 3, p. H214, 2012.Google Scholar
19. Maeda, T., Suzuki, E., Sakata, I., Yamanaka, M. and Ishii, K., in Nanotechnology, vol. 10, p. 127, 1999.Google Scholar
20. Sivakumar, R., Gopalakrishnan, R., Jayachandran, M., Sanjeeviraja, C., in Current Appl. Phys., vol. 7, p. 51, 2007.Google Scholar