Hostname: page-component-cd9895bd7-7cvxr Total loading time: 0 Render date: 2024-12-28T05:59:22.257Z Has data issue: false hasContentIssue false

A Novel Technology for Green(er) Manufacturing of CNTs via Recycling of Waste Plastics

Published online by Cambridge University Press:  28 January 2011

Chuanwei Zhuo
Affiliation:
Mechanical and Industrial Engineering, Northeastern University, 334 SN, 360 Huntington Ave., Boston, MA 02115, U.S.A.
Brendan Hall
Affiliation:
Mechanical and Industrial Engineering, Northeastern University, 334 SN, 360 Huntington Ave., Boston, MA 02115, U.S.A.
Yiannis Levendis
Affiliation:
Mechanical and Industrial Engineering, Northeastern University, 334 SN, 360 Huntington Ave., Boston, MA 02115, U.S.A.
Henning Richter
Affiliation:
Nano-C, Inc., 33 Southwest Park, Westwood, MA 02090, U.S.A.
Get access

Abstract

Costly and often highly-flammable chemicals, such as hydrogen and carbon-containing gases, are largely used for carbon supply in current carbon nanotube (CNT) synthesis technologies. To mitigate related economic and safety concerns, we have developed a versatile CNT synthesis sequence, where low-cost and safe-to-handle-and-store waste solid polymers (plastics) are used for in situ generation of hydrogen and carbon-containing gases. Introduction of different waste plastics, such as polyethylene, polypropylene and polystyrene, into a multi-stage pyrolysis/ combustion/synthesis reactor allows for efficient CNT formation. This process is largely exothermic and scalable. It uses low-cost stainless steel screens to serve both as substrates as well as catalysts for CNT synthesis. This technique enables a solution for both waste plastic utilization and sustainable CNT production.

Type
Research Article
Copyright
Copyright © Materials Research Society 2011

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

[1] Healy, ML, Dahlben, LJ, Isaacs, JA. Environmental assessment of single-walled carbon nanotube processes. J Ind Ecol. 2008;12(3):376–93.CrossRefGoogle Scholar
[2] Subramanian, PM. Plastics recycling and waste management in the US. Resour Conserv Recy. 2000;28(3–4):253–63.Google Scholar
[3] Zhuo, C., Hall, B., Richter, H., Levendis, Y. Synthesis of carbon nanotubes by sequential pyrolysis and combustion of polyethylene. Carbon. 2010;48(14):4024–34.CrossRefGoogle Scholar
[4] Goncalves, CK, Tenorio, JAS, Levendis, YA, Carlson, JB Emissions from the premixed combustion of gasified polyethylene. Energ Fuel. 2007;22(1):372–81.Google Scholar
[5] Kiang, JKY, Uden, PC, Chien, JCW. Polymer reactions–Part VII: Thermal pyrolysis of polypropylene. Polym Degrad Stabil.2(2):113–27.Google Scholar
[6] Liu, Y, Qian, J, Wang, J. Pyrolysis of polystyrene waste in a fluidized-bed reactor to obtain styrene monomer and gasoline fraction. Fuel Process Technol. 2000;63(1):45–55.CrossRefGoogle Scholar
[7] Hernadi, K, Fonseca, A, Nagy, JB, Siska, A, Kiricsi, I. Production of nanotubes by the catalytic decomposition of different carbon-containing compounds. Appl Catal A-Gen. 2000;199(2):245–55.Google Scholar
[8] Vander Wal, RL, Hall, LJ, Berger, GM. Optimization of flame synthesis for carbon nanotubes using supported catalyst. J Phys Chem B. 2002;106(51):13122–32.CrossRefGoogle Scholar
[9] Benito, AM, Maniette, Y, Muñoz, E, Martínez, MT Carbon nanotubes production by catalytic pyrolysis of benzene. Carbon. 1998;36(5–6):681–3.CrossRefGoogle Scholar
[10] Charinpanitkul, T, Sano, N, Puengjinda, P, Klanwan, J, Akrapattangkul, N, Tanthapanichakoon, W. Naphthalene as an alternative carbon source for pyrolytic synthesis of carbon nanostructures. J Anal Appl Pyrol. 2009;86(2):386–90.CrossRefGoogle Scholar
[11] Nasibulin, AG, Queipo, P, Shandakov, SD, Brown, DP, Jiang, H, Pikhitsa, PV, et al. . Studies on mechanism of single-walled carbon nanotube formation. J Nanosci Nanotechno. 2006;6(5):1233–46.CrossRefGoogle ScholarPubMed
[12] Amama, PB, Pint, CL, McJilton, L, Kim, SM, Stach, EA, Murray, PT, et al. . Role of Water in Super Growth of Single-Walled Carbon Nanotube Carpets. Nano Lett. 2008;9(1):44–9.CrossRefGoogle Scholar
[13] Zhang, G, Mann, D, Zhang, L, Javey, A, Li, Y, Yenilmez, E, et al. . Ultra-high-yield growth of vertical single-walled carbon nanotubes: Hidden roles of hydrogen and oxygen. P Natl Acad Sci USA. 2005;102(45):16141–5.CrossRefGoogle ScholarPubMed