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Ordered Thin Films of Perylenetetracarboxylicdianhydride-bisimide and bis-(N-alkyl)-Quinacridone Dyes

Published online by Cambridge University Press:  14 March 2011

Andrew Back ,
Dana Alloway ,
Derck Schlettwein ,
Brook Schilling ,
J.-F. Wang ,
Mike Carducci  and
Neal R. Armstrong
Andrew Back
Affiliation:
Department of Chemistry, University of Arizona, Tucson, Arizona 85721 Physical Electronics Corp., Eden Prairie, Minnesota
Dana Alloway
Affiliation:
Department of Chemistry, University of Arizona, Tucson, Arizona 85721
Derck Schlettwein
Affiliation:
Department of Chemistry, University of Arizona, Tucson, Arizona 85721 Institute für Angewandte und Physikalische Chemie, Universität Bremen, Bremen, Germany
Brook Schilling
Affiliation:
Department of Chemistry, University of Arizona, Tucson, Arizona 85721 Micromass Inc. Beverly, Mass
J.-F. Wang
Affiliation:
Department of Chemistry, University of Arizona, Tucson, Arizona 85721
Mike Carducci
Affiliation:
Department of Chemistry, University of Arizona, Tucson, Arizona 85721
Neal R. Armstrong
Affiliation:
Department of Chemistry, University of Arizona, Tucson, Arizona 85721
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Abstract

We review here the recent characterization of vacuum deposited monolayer and multilayer thin films of two different perylenetetracarboxylic-dianydride-bisimides (Cn-PTCDI; n =4,5), quinacridone, and two new bis-(N-alkyl)-quinacridone dyes (DIQA and DEHQA) on single crystal alkali halides using a combination of in situ luminescence spectroscopies and ex situ tapping mode AFM. Flat lying monolayer structures are indicated for PTCDA on the (100) faces of NaCl, KCl and KBr, for C4-PTCDI on KCl, for C5-PTCDI on both KCl and KBr and for DIQA on both KCl and KBr. Coherent thin films, exhibiting layer-by-layer growth can be achieved for PTCDA on all substrates, for C4-PTCDI on KCl and for DIQA on both KBr and KCl. Both C4-PTCDI and DIQA appear to fulfill the requirements for dyes which exhibit layered growth with the molecular plane inclined at steep angles to the surface normal.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 620: Symposium M – Morphology & Dynamics of Crystal Surfaces in Complex… , 2000 , M3.2.1
Copyright
Copyright © Materials Research Society 2000

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References

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