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Overview-Rigid Rod Polymers for Nonlinear Optics and Electronics

Published online by Cambridge University Press:  26 February 2011

Donald R. Ulrich
Donald R. Ulrich*
Affiliation:
Directorate of Chemical and Atmospheric Sciences, Air Force Office of Scientific Research, Bolling Air Force Base, Washington, D.C. 20032-6448
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Abstract

In 1979 the Air Force undertook a program to establish the principles for the design, synthesis, and processing of ultrastructured, electroactive polymers. The promising candidates were determined to be rigid rod polymers. In 1982 this approach was expanded to include the investigation of nonlinear optical properties in rigid rod polymers. The initial results in 1985, demonstrating the concept of multifunctionality, were quite startling. The polymers, PBT and PBO, which were designed as structural polymers with high strength, high modulus, and excellent thermaloxidative stability, were found to possess large nonresonant macroscopic third order optical susceptibilities. Their origin resides in the ultrafast, lossless excitations of highly-charged π- electron states. The state-of-the-art for nonlinear optical rigid rod polymers is reviewed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 134: Symposium J – Materials Science and Engineering of Rigid-Rod Polymers , 1988 , 589
Copyright
Copyright © Materials Research Society 1989

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References

REFERENCES

[1] Arnold, F. E., presented at the 1988 MRS Fall Meeting, Boston, MA, 1988 (to be published).Google Scholar
[2] Wolfe, J. F., ibid.Google Scholar
[3] Ulrich, D. R., Polymer, 28, 533 (1987).CrossRefGoogle Scholar
[4] Dalton, L. R., Yu, L. P., Polis, D. W., McLean, M. R., and Sapochak, L., presented at the 1988 MRS Fall Meeting, Boston, MA, 1988.Google Scholar
[5] Mark, J. E. and Welsh, W. J., ibid.Google Scholar
[6] Barker, R. E., Chen, D. Y. S., Hawk, J. A., Huang, C., and Huang, W., ibid.Google Scholar
[7] Belaish, I., Davidov, D., McLean, M. R., Dalton, L. R., and Nalwa, H. S., ibid.Google Scholar
[8] DePra, P. A., Romanko, W. R., Marks, T. J., and Carr, S. H., ibid.Google Scholar
[9] Stegeman, G. I., Zanoni, R., Rochford, K., and Seaton, C., in Nonlinear Optical Effects in Organic Polymers, edited by Messier, J., Kajzar, F., Prasad, P., and Ulrich, D. (Kluwer Academic Publishers, Dordrecht, 1989), pp. 257–276.CrossRefGoogle Scholar
[10] Stegeman, G. I., Zanoni, R., Finlayson, N., Wright, E. M., and Seaton, C. T., J. of Lightwave Tech. 6, 953, 1988.CrossRefGoogle Scholar
[11] Lytel, R. and Stegeman, G. I., in Nonlinear Optical Effects Organic Polymers, edited by Messier, J., Kajzar, F., Prasad, P., and Ulrich, D. (Kluwer Academic Publishers, Dordrecht, 1989), pp. 379–381.CrossRefGoogle Scholar
[12] Cao, X. F., Jiang, J. P., Bloch, D. P., Hellwarth, R. W., Yu, L. P., and Dalton, L. R., J. App. Phys. (in press).Google Scholar
[13] Yu, L. P. and Dalton, L. R., Synthetic Metals, 29, E463, 1989.CrossRefGoogle Scholar
[14] Prasad, P., in Proceedings of the Fourth International Conference on the Ultrastructure Processing of Ceramics. Glass. and Composites, edited by Uhlmann, D. R. and Ulrich, D. R. (Wiley-Interscience, New York, 1989), (in press).Google Scholar
[15] Rao, D. N., Swiatkiecz, J., Chopra, P., Ghoshal, S. K., and Prasad, P. N., Appl. Phys. Lett. 48, 1187 (1986).CrossRefGoogle Scholar
[16] Garito, A. F., Wong, K. Y., Cai, Y. M., Man, H. T., and Zamani, O., in Molecular and Polymeric Optoelectronic Materials: Fundamentals and Applications, Proceedings SPIE, 682, August 1986, edited by Khanarian, G., pp 2–11.Google Scholar
[17] Yu, L. P. and Dalton, L. R., Synthetic Metals, 29, E463, 1989.CrossRefGoogle Scholar
[18] Melo, C. P. De and Silby, R., Chem. Phys. Lett., 140, 537, 1987.CrossRefGoogle Scholar
[19] Hellwarth, R. W. and Dalton, L. R., Private Communication.Google Scholar
[20] Prasad, P. N., in Nonlinear Optical and Electroactive Polymers, edited by Prasad, P. N. and Ulrich, D. R. (Plenum Press, New York, 1987), pp. 41–68.Google Scholar
[21] Garito, A. F., Heflin, J. R., Wong, K. Y., and Zamani-Khamiri, O., in Nonlinear Optical Properties of Organic Materials, SPIE, 971, 1988, pp. 2–10.Google Scholar
[22] Garito, A. F., Final Report, Air Force contract F49620-85-C-0105, 1 May 1985-30 April 1988.Google Scholar
[23] Otsuka, K., Yumoto, J., and Song, J., Optics Letters, 10, 508, 1985.CrossRefGoogle Scholar
[24] Dalton, L. R., Annual Technical Report, Air Force contracts F49620-85-C-0105 and F49620-87-C-0071.Google Scholar
[25] J. A. Medrano and Reale, J. F., presented at 1988 MRS Fall Meeting, Boston, MA, 1988.Google Scholar
[26] J. Kane and Feld, W., private communication.Google Scholar