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Polystyrene-Poly(Vinylphenol) Copolymers as Compatibilizers for Organic-Inorganic Composites

Published online by Cambridge University Press:  10 February 2011

Christine J. T. Landry ,
Bradley K. Coltrain  and
David M. Teegarden
Christine J. T. Landry
Affiliation:
Eastman Kodak Company, Rochester, New York 14650-2116.
Bradley K. Coltrain
Affiliation:
Eastman Kodak Company, Rochester, New York 14650-2116.
David M. Teegarden
Affiliation:
Eastman Kodak Company, Rochester, New York 14650-2116.
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Abstract

Random, graft, and block copolymers of polystyrene (PS) and poly(4-vinylphenol) (PVPh), and PVPh homopolymer are shown to act as compatibilizers for incompatible organic-inorganic composite materials. The VPh component reacts, or interacts strongly with the polymerizing inorganic (titanium or zirconium) alkoxide. The organic components studied were PS, poly(vinyl methyl ether), and poly(styrene-co-acrylonitrile). The use of such compatibilizers provides a means of combining in situ polymerized inorganic oxides and hydrophobic polymers. This is seen as a reduction in the size of the dispersed inorganic phase and results in improved optical and mechanical properties.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 435: Symposium V – Better Ceramics Through Chemistry VII , 1996 , 507
Copyright
Copyright © Materials Research Society 1996

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References

1. Sun, C. -C. and Mark, J. E., Polymer 30, p. 104 (1989).Google Scholar
2. Huang, H. H., Orler, B. and Wilkes, G. L., Macromolecules 20, p. 1322 (1987).Google Scholar
3. Coltrain, B. K., O'Reilly, J. M., Turner, S. R., Sedita, J. S., Smith, V. K., Rakes, G. A. and Landry, M. R., in Proc.5th Annu. Int. Conf. Crosslinked Polym., Switzerland (1991), 11.Google Scholar
4. Rodrigues, D. E., Brennan, A. B., Betrabet, C., Wang, B., and Wilkes, G. L., Chem. Mater. 4, p. 1437 (1992).Google Scholar
5. Fitzgerald, J. J., Landry, C. J. T. and Pochan, J. M., Macromolecules, 25 p. 3715 (1992).Google Scholar
6. Landry, C. J. T., Coltrain, B. K. and Brady, B. K., Polymer 33, p. 1486 (1992).Google Scholar
7. Toki, M., Chow, T. Y., Ohnaka, T., Samura, H. and Saegusa, T., Polym. Bull. 29, p. 653 (1992).Google Scholar
8. Coltrain, B. K., Ferrar, W. T., Landry, C. J. T., Molaire, T. R. and Zumbulyadis, N., Chem. Mater., 4, p. 358 (1992).Google Scholar
9. Mauritz, K. A., Storey, R. F. and Jones, C. K., ACS Symp. Ser. 395, p. 401 (1989).Google Scholar
10. David, I. A. and Scherer, G. W., Polym. Prepr. 32, p. 530 (1991).Google Scholar
11. Landry, C. J. T., Coltrain, B. K., Teegarden, D. M., Long, T. E., Long, V. K., accepted for publication in Macromolecules.Google Scholar
12. Wang, B., Gungor, A., Brennan, A. B., Rodrigues, D. E., McGrath, J. E., and Wilkes, G. L., Polym. Prepr. 32, p. 521 (1991).Google Scholar