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Preparation and Characterization of Aluminum Lithium Hydroxide Carbonate Hydrate Obtained From Basic Aluminum Sulfate

Published online by Cambridge University Press:  31 January 2012

César A. C. Soto ,
Aurora P. Delgado ,
Esthela R. Ramírez  and
Veridiana R. Zamudio
César A. C. Soto
Affiliation:
Universidad de Guanajuato, Departamento de Química, Noria alta s/n, Col. Noria alta, Guanajuato, Gto., C.P. 36050, México. E-mail: csarc376@gmail.com
Aurora P. Delgado
Affiliation:
Universidad de Guanajuato, Departamento de Química, Noria alta s/n, Col. Noria alta, Guanajuato, Gto., C.P. 36050, México. E-mail: csarc376@gmail.com
Esthela R. Ramírez
Affiliation:
Universidad de Guanajuato, Departamento de Química, Noria alta s/n, Col. Noria alta, Guanajuato, Gto., C.P. 36050, México. E-mail: csarc376@gmail.com
Veridiana R. Zamudio
Affiliation:
Universidad de Guanajuato, Departamento de Química, Noria alta s/n, Col. Noria alta, Guanajuato, Gto., C.P. 36050, México. E-mail: csarc376@gmail.com
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Abstract

Aluminum lithium hydroxide carbonate hydrate, also known as Al-Li double hydroxide or Al-Li hydrotalcite-like compound [Al2Li(OH)6]2CO3•nH2O, was prepared from basic aluminum sulfate. This compound was prepared by precipitation in homogeneous solution of an aluminum bisulfite solution. A sodium aluminate aqueous solution was prepared by dissolving basic aluminum sulfate in 1M sodium hydroxide. The Al-Li double hydroxide was obtained after addition of lithium carbonate satured solution to the sodium aluminate solution, at 60 °C. The synthesized powder was characterized by thermal analysis (TG, DTG and DTA), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). By this method crystalline Li-Al hydrotalcite like compound with composition near to Al4Li2(OH)12CO3 •3H2O was obtained.

Keywords

Chemical synthesisThermogravimetric analysis (TGA)Scanning electron microscopy (SEM)Transmission electron microscopy (TEM)
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1372: Symposium S3 – Structural and Chemical Characterization of Metal Alloys and Compounds—2011 , 2012 , imrc-1372-s3-47
Copyright
Copyright © Materials Research Society 2012

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References

REFERENCES

1. Ingram, L., Taylor, HFW., Mineral Mag. 36, 465–479 (1967).Google Scholar
2. Besserguenev, A.V., Fogg, A. M., Francis, R. J., Price, S. J., O’Hare, D., Isupov, V. P. and Tolochko, B. P., Chem Mater 9, 241 (1997).Google Scholar
3. Climent, M. J., Corma, A., De Frutos, P., Iborra, S., Noy, M., Velty, A., Concepcion, P., Journal of Catalysis 269 (1), 140-149 (2010).Google Scholar
4. Miyata, S., Taketomi, M., Kojima, T., Tanizaki, S., Hashimoto, A., Kamishiro, K., Eguchi, M., Suzuki, S., Jpn. Patent No. 2000233188 (29 August 2000).Google Scholar
5. Del Arco, M., Cebadera, E., Gutierrez, S., Martin, C., Montero, MJ., Rives, V., Rocha, J., Sevilla, MA., J Pharm Sci 93, 1649–1658 (2004).Google Scholar
6. Duan, X. et al. ., “Layered Double Hydroxides”, ed. Duan, X. and Evans, D. G. (Springer-Verlag Berlin Heidelberg, 2006) pp. 90–109.Google Scholar
7. Nyquist, R. A. and Kagel, R. O., “Infrared Spectra of Inorganic Compounds”, (Academic Press, 1971) pp. 1-5.Google Scholar
8. Nakamoto, K., “Infrared and Raman Spectra of Inorganic and Coordination compounds”, (John Wiley & Sons, 1963) pp. 103-110.Google Scholar
9. Frost, R. L., Weier, M. L., and Kloprogge, J. T., Journal of Raman Spectroscopy 34 (10), 760-768 (2003).Google Scholar
10. Kloprogge, J. T., Wharton, D., Hickey, L. and Frost, R. L., American Mineralogist 87 (5–6), 623-629 (2002).Google Scholar
11. Serna, C. J., Rendon, J. L. and Iglesias, J. E., Clays and Clay Minerals 30 (3), 180-184 (1982).Google Scholar
12. Drewien, C. A., Tallant, D. R., Eatough, M. O., Journal of Materials Science 31 (16), 4321-4325 (1996).Google Scholar
13. Miyata, S., Clays and Clay Minerals 28, 50–56 (1980).Google Scholar