Hostname: page-component-cd9895bd7-mkpzs Total loading time: 0 Render date: 2024-12-29T08:15:03.652Z Has data issue: false hasContentIssue false
  • English
  • Français

Preparation and Characterization of Tin/Carbon Composites for Lithium-Ion Cells

Published online by Cambridge University Press:  01 February 2011

Ronald A. Guidotti ,
David J. Irvin ,
William R. Even Jr  and
Karl Gross
Ronald A. Guidotti
Affiliation:
Sandia National Laboratories, P.O. Box 5800, Albuquerque, NM 87185-0614
David J. Irvin
Affiliation:
Naval Air Warfare Center, Polymer Science and Engineering Branch, China Lake, CA 93555
William R. Even Jr
Affiliation:
Sandia National Laboratories, P.O. Box 969, Livermore, CA 94551
Karl Gross
Affiliation:
Sandia National Laboratories, P.O. Box 969, Livermore, CA 94551
Get access

Abstract

A number of Sn/C composites were prepared for evaluation as anode materials for Li-ion cells. In one case, samples were prepared by incorporation of Sn species into organic precursors that were then pyrolyzed under an Ar/H2 cover gas to prepare the Sn/C composites. They were also prepared by decoration of various types of carbon with nanoparticles of Sn by electroless deposition using hydrazine. The carbons examined included a disordered carbon prepared in house from poly(methacrylonitrile), a mesocarbon microbead (MCMB) carbon, and a platelet graphite. The Sn/C composites were examined by x-ray diffraction (XRD) and scanning electron microscopy (SEM) and were also analyzed for Sn content. They were then tested as anodes in three-electrode cells against Li metal using 1M LiPF6 in ethylene carbonate (EC)/dimethyl carbonate (DMC) solution. The best overall electrochemical performance was obtained with a Sn/C composite made by electroless deposition of 10% Sn onto platelet graphite.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 730: Symposium V – Materials for Energy Storage, Generation, and Transport , 2002 , V1.11
Copyright
Copyright © Materials Research Society 2002

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Veeraraghavan, B., Durairajan, A., White, R.E., Popov, B. N., and Guidotti, Ronald, “Synthesis and Characterization of Sn-Coated SFG10 Graphites as Negative Electrodes in Li-Ion Cells,” 198th Meeting of The Electrochemical Society, Phoenix, AZ, October 22-27, 2000.Google Scholar
2. Irvin, D. J., Even, W. R., Gross, K., and Guidotti, R. A., “Tin/Carbon Composites: Crystalline Sphere to Amorphous Powders,” SAND2001-8397 (August 2001).Google Scholar
3. Even, W. R. and Gregory, D. P., MRS Bull., 19(4), 29 (1994).Google Scholar