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Profiling of Anode Surface Cycled in LiBOB-based Electrolyte of Li Ion Batteries

Published online by Cambridge University Press:  01 February 2011

Unchul Lee ,
Kang Xu ,
Sheng S. Zhang  and
T. Richard
Unchul Lee
Affiliation:
Jow Sensor and Electronic Devices Directorate, U. S. Army Research Laboratory, Adelphi, MD 20783–1197
Kang Xu
Affiliation:
Jow Sensor and Electronic Devices Directorate, U. S. Army Research Laboratory, Adelphi, MD 20783–1197
Sheng S. Zhang
Affiliation:
Jow Sensor and Electronic Devices Directorate, U. S. Army Research Laboratory, Adelphi, MD 20783–1197
T. Richard
Affiliation:
Jow Sensor and Electronic Devices Directorate, U. S. Army Research Laboratory, Adelphi, MD 20783–1197
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Abstract

As the youngest battery chemistry, Li ion technology was made possible by the formation of stable electrode/electrolyte interfaces. The correlation between the electrochemistry and the surface profile of the graphitic anode was studied in this work with a new salt lithium bis (oxalate) borate (LiBOB).

In an attempt to depict a dynamic picture of the formation of graphite/electrolyte interface during the initial forming cycle, we employed X-ray photoelectron spectroscopy in combination with the “pre-formation” technique to establish the dependence of the surface chemistry on the forming potential of the anode. A progressive transition in the 1s electron binding energies of the major elements was observed as the lithiation proceeds; however, the surface chemical species as well as their abundances seemed to stabilize around 0.55 V and remained constant during the subsequent delithiation process, indicating that a stable solid electrolyte interface (SEI) exists thereafter. Integrating the information revealed by different analyses, we believe that the reductive decomposition of BOB−-anion starts at ca. 1.00 V, while the effective protection of graphene surface by SEI is available after the anode is lithiated below the potential of 0.55 V.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 835: Symposium K – Solid-State Ionics , 2004 , K6.10
Copyright
Copyright © Materials Research Society 2005

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References

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