Hostname: page-component-6bf8c574d5-w79xw Total loading time: 0 Render date: 2025-02-22T08:02:36.042Z Has data issue: false hasContentIssue false
  • English
  • Français

Scattering Studies on Mixtures of Poly(Ethylene Oxide) with Poly(Methyl Methacrylate)

Published online by Cambridge University Press:  26 February 2011

T. P. Russell ,
H. Ito  and
G. D. Wignall
T. P. Russell
Affiliation:
IBM Almaden Research Center, 650 Harry Road, San Jose, California 95120-6099
H. Ito
Affiliation:
IBM Almaden Research Center, 650 Harry Road, San Jose, California 95120-6099
G. D. Wignall
Affiliation:
NCSASR, Oak Ridge National Laboratory, Oakridge, Tennessee 37830
Get access

Abstract

Molten and semi-crystalline mixtures of PEO and PMMA have been investigated by small angle neutron and X-ray scattering. It has been found that the Flory Huggins interaction parameter, evaluated from the intermolecular scattering function, is quite small and is apparently dominated by entropic contributions. Scattering profiles from the semi-crystalline mixtures clearly show that the PMMA is incorporated within the amorphous phase between the crystalline PEO lamellae.

Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 79: Symposium F – Scattering, Deformation and Fracture in Polymers , 1986 , 87
Copyright
Copyright © Materials Research Society 1987

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

[1] Alfonso, G. C. and Russell, T. P., Macromolecules 16, 1143 (1986).Google Scholar
[2] Ito, H., Russell, T. P. and Wignall, G. D., Macromolecules (submitted).Google Scholar
[3] Koehler, W. C., Physica 137b, 320 (1986).Google Scholar
[4] Hayashi, H., Flory, P. J. and Wignall, G. D., Macromolecules, 16, 1328 (1983).Google Scholar
[5] Benoit, H. and Benmouna, M., Polymer 25, 1059 (1984).Google Scholar
[6] Benoit, H. and Benmouna, M., Macromolezules 17, 535 (1984).Google Scholar
[7] Warner, M., Higgins, J. S. and Carter, A. J., Macromolecules, 16, 1931 (1983).Google Scholar
[8] Hadziioannou, G. and Stein, R. S., Macromolecules 17, 567 (1984).CrossRefGoogle Scholar
[9] Lefebvre, J. M., Porter, R. S. and Wignall, G. D. (in preparation).Google Scholar
[10] Lefebvre, J. M., Porter, R. S., Wignall, G. D. and Russell, T. P. (unpublished results).Google Scholar
[11] Bawendi, M. and Freed, K. F., J. Chem. Phys. (submitted).Google Scholar
[12] Strobl, G. R. and Schneider, M., J. Polym. Sci., Polym. Phys. Ed. 18, 1343 (1980).CrossRefGoogle Scholar