Hostname: page-component-745bb68f8f-grxwn Total loading time: 0 Render date: 2025-01-15T07:07:32.432Z Has data issue: false hasContentIssue false
  • English
  • Français

Structural Characterization Of Zeolites Using Raman Scattering

Published online by Cambridge University Press:  15 February 2011

H. W. Deckman ,
J. A. Creighton ,
R. G. Buckley  and
J. M. Newsam
H. W. Deckman
Affiliation:
Corporate Research, Exxon Research And Engineering Co., Annandale, NJ
J. A. Creighton
Affiliation:
University Of Kent, Canterbury, U.K.
R. G. Buckley
Affiliation:
Department Of Scientific And Industrial Research, New Zealand
J. M. Newsam
Affiliation:
BIOSYM Technologies, San Diego, CA
Get access

Abstract

We show that the frequencies of certain optically active lattice vibrational modes in a large number of zeolites can be used as direct structural probes. Mode frequencies are found to depend on the cosine of the T-O-T angle and the Si/Al ratio of the framework. The relationship between mode frequency and local framework structure is discussed in terms of a complete lattice dynamics calculation for specific zeolite structures as well as a lattice dynamical model of amorphous glasses.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 233: Symposium U – Synthesis/Characterization and Novel Applications of Molecular Sieve Materials , 1991 , 295
Copyright
Copyright © Materials Research Society 1991

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Flanigen, E. M., Khatami, H., and Szymanski, H. A., in Molecular Sieve Zeolites 1 edited by Flanigen, E. M. and Sand, L. B. (Adv. Chem. Ser. 101 Amer. Chem. Soc., Washington DC 1971), pp. 201–229.CrossRefGoogle Scholar
2. Flanigen, E. M. in Zeolite Chemistry and Catalysis, edited by Rabo, J. A. (ACS Monograph No. 171 Amer. Chem. Soc., Washington DC 1976), pp. 80–118.Google Scholar
3. Henderson, C. M. B. and Taylor, D., Spectrochemica Acta 36A, 929 (1979).CrossRefGoogle Scholar
4. Angell, C. L., J. Phys. Chem. 77, 222 (1979).Google Scholar
5. Blackwell, C. S., J. Phys. Chem. 83 3257 (1979).Google Scholar
6. Miecznikowski, A. and Hanzua, J., Zeolites 5, 188 (1985).Google Scholar
7. Buckley, R. G., Deckman, H. W., Newsam, J. M., McHenry, J. A., Persans, P. D., and Witzke, H., in Microstructure and Properties of Catalysts edited by Treacy, M., Thomas, J., and White, J. (Mat. Res. Soc. Proc. 111, Pittsburgh, PA 1988) pp. 141–147.Google Scholar
8. Barrio, R. A., Galeener, F. L., And Martinez, E., Phys. Rev. Lett. 52 1786 (1984).Google Scholar
9. Dutta, P. K., Shieh, D. C., Puri, M., Zeolites 8, 306 (1988).CrossRefGoogle Scholar
10. Creighton, J. A., Deckman, H. W., Newsam, J. M. (to be published).Google Scholar
11. Maroni, V. A., Appl. Spectrosc. 42, 487 (1988).Google Scholar
12. Creighton, J. A., Deckman, H. W., and Newsam, J. M., J. Phys. Chem. Letters 95,2099 (1991).Google Scholar
13. Buckley, R. G., Deckman, H. W., McHenry, J. A. and Witzke, H., J. Phys. Chem. Letters 94, 8384 (1990).Google Scholar