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Structural Requirements for Surface-Induced Aromatic Stabilization

Published online by Cambridge University Press:  28 March 2014

Takuya Hosokai ,
Keiichirou Yonezawa ,
Kengo Kato ,
Rintaro Makino ,
Jinpeng Yang ,
Kaveenga Rasika Koswattage ,
Alexander Gerlach ,
Frank Schreiber ,
Nobuo Ueno  and
Satoshi Kera
Takuya Hosokai
Affiliation:
Department of Materials Science and Technology, Iwate University, 4-3-5 Ueda, Morioka, 0208551 Iwate, JAPAN
Keiichirou Yonezawa
Affiliation:
Department of Nanomaterial Science, Graduate School of Advanced Integration Science, Chiba University, 1-33 Yayoi-cho, Inage-ku, 2638522 Chiba, JAPAN
Kengo Kato
Affiliation:
Department of Nanomaterial Science, Graduate School of Advanced Integration Science, Chiba University, 1-33 Yayoi-cho, Inage-ku, 2638522 Chiba, JAPAN
Rintaro Makino
Affiliation:
Department of Nanomaterial Science, Graduate School of Advanced Integration Science, Chiba University, 1-33 Yayoi-cho, Inage-ku, 2638522 Chiba, JAPAN
Jinpeng Yang
Affiliation:
Department of Nanomaterial Science, Graduate School of Advanced Integration Science, Chiba University, 1-33 Yayoi-cho, Inage-ku, 2638522 Chiba, JAPAN
Kaveenga Rasika Koswattage
Affiliation:
Department of Nanomaterial Science, Graduate School of Advanced Integration Science, Chiba University, 1-33 Yayoi-cho, Inage-ku, 2638522 Chiba, JAPAN
Alexander Gerlach
Affiliation:
Institut für Angewandte Physik, Universität Tübingen, Auf der Morgenstelle 10, Tübingen 72076, GERMANY
Frank Schreiber
Affiliation:
Institut für Angewandte Physik, Universität Tübingen, Auf der Morgenstelle 10, Tübingen 72076, GERMANY
Nobuo Ueno
Affiliation:
Department of Nanomaterial Science, Graduate School of Advanced Integration Science, Chiba University, 1-33 Yayoi-cho, Inage-ku, 2638522 Chiba, JAPAN
Satoshi Kera
Affiliation:
Department of Nanomaterial Science, Graduate School of Advanced Integration Science, Chiba University, 1-33 Yayoi-cho, Inage-ku, 2638522 Chiba, JAPAN
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Abstract

Surface-induced aromatic stabilization (SIAS), a recently proposed mechanism leading to a formation of charge-transfer (CT) states at organic/metal (O/M) interfaces [G. Heimel, et al., Nat. Chem.5, 187 (2013)], was investigated for an aromatic hydrocarbon, diindenoperylene (DIP), by means of synchrotron radiation-based ultraviolet photoelectron spectroscopy (UPS). By employing DIP and noble metal substrates (Ag and Cu), we confirmed the formation of CT states, indicating that an inclusion of a specific functional group with a hetero-atom within adsorbate molecules as suggested before is not necessarily required for the formation of CT states mediated by the SIAS. With a comparison of the mother and analogue molecules, perylene and PTCDA, we discuss the structural requirement for the realization of the SIAS.

Keywords

adsorptionphotoemissionsurface chemistry
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1647: Symposium GG – Surface/Interface Characterization and Renewable Energy , 2014 , mrsf13-1647-gg01-03
Copyright
Copyright © Materials Research Society 2014 

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References

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