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Structure Effects of High Surface Area Molybdenum Nitride Powders, Macrocrystals and Nanoparticles as Catalysts for Thiophene Desulfurization

Published online by Cambridge University Press:  15 February 2011

K. L. Roberts  and
E. J. Markel
K. L. Roberts
Affiliation:
Chemical Engineering Department, N.C. A&T State University, Greensboro, NC 27411, kroberts@ncat.edu
E. J. Markel
Affiliation:
Exxon Polymer Research Center, Exxon Research and Engineering Company, Baytown, TX 77520
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Abstract

Mo2N powder, macrocrystals and nanoparticles and porous Mo metal were synthesized using temperature programmed reduction of MoO3 powder and crystals with reactant feed gases consisting of NH3 N2/H2 mixtures and pure H2. The Mo-based catalysts were characterized using BET, XRD, TGA, SEM, and STM. The Mo-based catalysts were also analyzed for the hydrodesulfurization (HDS) of thiophene. The relatively lower surface area Mo2N macrocrystalline catalysts (SSA = 44 m2/g) have a greater area specific activity than that of the higher surface area Mo2N powder catalysts (SSA = 150 m2/g) for the HDS of thiophene. Mo metal catalysts have significantly lower activity for thiophene HDS than Mo 2N catalysts and the HDS selectivities of non-sulfided Mo metal catalysts are significantly different from those of Mo 2N catalysts.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 549: Symposium FF – Advanced Catalytic Materials - 1998 , 1998 , 51
Copyright
Copyright © Materials Research Society 1999

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