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Successful Design of New Very Low Thermal Expansion Ceramics
Published online by Cambridge University Press: 22 February 2011
Abstract
In the last few years we have succeeded in developing three separate groups of near-zero-expansion ceramics. These are based on: (1) Modification by crystalline solution of GeO2 for SiO2 in the well-known cordierite phase. (2) Discovery of a new structural family known as [NZP] or [CTP], many members of which have near-zero values of a and very extensive crystalline solution possibilities permitting continuous control of α. (3) Di- (or multi) pfiasic composites of phases, one with negative and one with positive a to give a net-zero-α ceramic material.
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