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Surface Coatings Based on Polysilsesquioxanes: Grafting-from Approach Starting from Organic Polymers

Published online by Cambridge University Press:  31 January 2011

Daniel Kessler  and
Patrick Theato
Daniel Kessler
Affiliation:
kessled@uni-mainz.de, Johannes Gutenberg University Mainz, Institute of Organic Chemistry, Mainz, Germany
Patrick Theato
Affiliation:
theato@uni-mainz.de, Johannes Gutenberg University Mainz, Institute of Organic Chemistry, Mainz, Germany
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Abstract

Poly(methylsilsesquioxane) (PMSSQ) based hybrid materials are promising candidates to produce substrate-independent stable and adherent surface coatings. Usually these materials are synthesized by controlled radical polymerization from inorganic precursors. The presented synthetic pathway in here demonstrates how to graft PMSSQ networks from an endgroup-functionalized organic polymer and thus enlarges the range of accessible inorganic/organic hybrid coating materials.

Keywords

adhesionsol-gelsurface chemistry
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1190: Symposium NN – Active Polymers , 2009 , 1190-NN10-02
Copyright
Copyright © Materials Research Society 2009

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