Hostname: page-component-cd9895bd7-p9bg8 Total loading time: 0 Render date: 2024-12-28T00:30:38.872Z Has data issue: false hasContentIssue false
  • English
  • Français

Synthesis and Characterization of a New Family of Microporous Zirconium Silicates

Published online by Cambridge University Press:  15 February 2011

David S. Bern ,
Robert L. Bedard ,
Robert W. Broach ,
E. Alejandro Leon-Escamilla ,
Jana L. Gisselquist  and
Joe Plutht
David S. Bern
Affiliation:
UOP LLC, Des Plaines, Illinois
Robert L. Bedard
Affiliation:
UOP LLC, Des Plaines, Illinois
Robert W. Broach
Affiliation:
UOP LLC, Des Plaines, Illinois
E. Alejandro Leon-Escamilla
Affiliation:
UOP LLC, Des Plaines, Illinois
Jana L. Gisselquist
Affiliation:
UOP LLC, Des Plaines, Illinois
Joe Plutht
Affiliation:
University of Chicago, Chicago, Illinois
Get access

Abstract

A family of microporous zirconium-silicate framework materials designated as UZSi (UOP zirconium silicates) has been synthesized and structurally characterized. A general hydrothermal synthesis approach yielded a variety of known and novel zirconium-silicate topologies consisting of ZrOa23(oct) and SiO20(tet) units. A novel microporous framework (UZSi-9, Na2ZrSi3O9·x H2O) has been synthesized and structurally characterized. This framework contains A- and A-propeller units, which can also be found in the framework of the compositionally similar UZSi-1 1 (Na2ZrSi3O9·x H2O). Both UZSi-9 and UZSi-II adsorb and desorb water with a Type I microporous isotherm.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 549: Symposium FF – Advanced Catalytic Materials - 1998 , 1998 , 73
Copyright
Copyright © Materials Research Society 1999

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. (a) Anthony, R.G., Philip, C.V., Dosch, R. G., Waste Mgt., 13, 503 (1993).Google Scholar
(b) Bortun, A.I., Bortun, L.N., Clearfield, A., Solvent Extraction and Ion Exchange, 14(2), 341-354 (1996).Google Scholar
2. (a) Lambert, S. L., U.S. Patent No. 5,338,527 (16 August 1994);Google Scholar
(b) Rocha, J., Ferreira, P., Lin, Z., Agger, J. R., Anderson, M. W., Chem. Commun. 12, 1269-1270 (1998);Google Scholar
(c) Ilyushin, G. D., Demyanets, L. N., Kristallografiya, 42 (6), 1124-1129 (1997).Google Scholar
(d) Poojary, D.M., Bortun, A.I., Bortun, L.N., Clearfield, A. Inorg. Chem. 36, 3072-3079 (1997).Google Scholar
(e) Bortun, A.I., Bortun, L.N., Clearfield, A., Chem. Mater., 36, 3072-3079 (1997).Google Scholar
3. Ilyushin, G.D., Neorganicheskie Materialy, 29, 971–975 (1992).Google Scholar
4. (a) Poojary, D.M., Bortun, A.I., Bortun, L.N., Clearfield, A., Inorg. Chem., 36, 3072–3079 (1997).Google Scholar
(b) Lin, Z., Rocha, J., Brandao, P., Ferreira, A., Esculcas, A.P., Pedrosa de Jesus, J.D., J. Phys, Chem. B, 101, 7114-7120 (1997).Google Scholar
5. (a) Rocha, J., Ferreira, P., Lin, Z., Agger, J. R., Anderson, M.W., Chem Commun., 12, 1269–1270 (1998).Google Scholar
(b) Chao, G.Y., Conlon, R.P., The Mineralogical Record, 21, 363 (1970).Google Scholar
6. UOP paper on UZSi-9 crystal structure solution in preparation.Google Scholar
7. Breck, D.W., Zeolite Molecular Sieves, (Wiley-Interscience Publication, New York 1974), p. 14–15.Google Scholar
8. Breck, D.W., Zeolite Molecular Sieves, (Wiley-Interscience Publication, New York 1974), p. 415.Google Scholar
9. (a) Rocha, J., Ferreira, P., Lin, Z., Agger, J.R., Anderson, M.W., Chem Commun., 12, 1269–1270 (1998).Google Scholar
(b) Chao, G.Y., Chen, T.T., Baker, J., Can. Mineral., 18, 497 (1980).Google Scholar