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Synthesis and Characterization of Titanium Oxo-Alkoxides through Solvatothermal Process

Published online by Cambridge University Press:  10 February 2011

N. Steunou ,
Y. Dromzee ,
F. Robert  and
C. Sanchez
N. Steunou
Affiliation:
Chimie de la Matière Condensée (URA CNRS 1466) Université Pierre et Marie Curie. 4, place Jussieu. 75252 PARIS. FRANCE.
Y. Dromzee
Affiliation:
Chimie des Métaux de Transition (URA CNRS 419). Université Pierre et Marie Curie. 4, place Jussieu. 75252 PARIS. FRANCE.
F. Robert
Affiliation:
Chimie des Métaux de Transition (URA CNRS 419). Université Pierre et Marie Curie. 4, place Jussieu. 75252 PARIS. FRANCE.
C. Sanchez
Affiliation:
Chimie de la Matière Condensée (URA CNRS 1466) Université Pierre et Marie Curie. 4, place Jussieu. 75252 PARIS. FRANCE.
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Abstract

The non hydrolytic synthesis of several titanium oxo-alkoxo clusters Ti3O(OPri) 8(OR)2, Ti11O13(OPri)18, Ti7O4(OEt)20 and Ti16O16(OEt )32 have been performed via thermolysis of different titanium alkoxides (Ti(OEt)4, Ti(OPri)4). The structures of these clusters were mainly determined by X-ray diffraction, 17O NMR and 13 C NMR.

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Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 435: Symposium V – Better Ceramics Through Chemistry VII , 1996 , 487
Copyright
Copyright © Materials Research Society 1996

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