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Synthesis and Nanostructure Control of CIGS Nanoparticles by Solvothermal Route

Published online by Cambridge University Press:  19 June 2015

Liangmin Zhang
Affiliation:
Department of Physics and Geology, California State University - Stanislaus, One University Circle, Turlock, CA 95382, U.S.A
Lifeng Dong
Affiliation:
Department of Physics, Astronomy, and Materials Science, Missouri State University, 901 S. National Avenue, Springfield, MO 65897, U. S. A.
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Abstract

Due to the potential applications to high-efficiency and light-weight solar cells, the growth of CuInGaSe2 (CIGS) nanoparticles is a recent research focus. We have developed a relatively simple solvothermal route to grow high quality CIGS nanoparticles in an autoclave under different temperatures (170 – 280°C). The effect of reaction temperature on the shape of CIGS nanoparticles has been investigated. At lower temperatures, the CIGS particles show plate-like shape. Whereas at higher temperatures, most of them exhibit rod-like feature. The nanoparticle products have been also characterized by field emission scanning electron microscopy and X-ray diffraction techniques.

Type
Articles
Copyright
Copyright © Materials Research Society 2015 

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References

REFERENCES

Romeo, A., Terheggen, M., Abou-Ras, D., Batzner, D. L., Haug, F. J., Kalin, M., Rudmann, D., and Tiwari, A. N., “Development of thin film Cu(In,Ga)Se2 and CdTe solar cells,” Prog. Photovolt: Res. Appl. 12, 93(2004).CrossRefGoogle Scholar
Jackson, P., Hariskos, D., Lotter, E., Paetel, S., Wuerz, R., Menner, R., Wischmann, W., and Powalla, M., “New world record efficiency for Cu(In,Ga)Se2 thin film solar cells beyond 20%,” Prog. Photovolt: Res. Appl. 19, 894(2011).CrossRefGoogle Scholar
Bar, M., Repins, I., Contreras, M. A., Weinhardt, L., Noufi, R., and Heske, C., “Chemical and electronic surface structure of 20%-efficient Cu(In,Ga)Se2 thin film solar cell absorbers,” Appl. Phy. Lett., 95, 052106(2009).CrossRefGoogle Scholar
Ennaoui, A., Fiechter, S., Pettenkofer, C., Alonso-Vante, N., Buker, K., Bronold, M., Hopfner, C. and Tributsch, H., “Iron disulfide for solar energy conversion, Solar Energy Materials and Solar Cells,” 29, 289(1993).CrossRefGoogle Scholar
Gloeckler, M., PhD dissertation, “Device physics of CIGS solar cells,” Colorado State University, Colorado, USA (2005).Google Scholar
Juhaiman, L. A., Scoles, L., Kingston, D., Patarachao, B., Wang, D., and Bensebaa, F., “Green synthesis of tunable CIGS nanoparticles using non-organic solvents,” Green Chem., 12, 1248(2010).CrossRefGoogle Scholar
Siritanon, T., Sarakonsri, T., and Thanachayanont, C., “The preparation of CIGS by a solution route method,” J. Cera. Proc. Research, 10, 437(2009).Google Scholar
Kim, K. H., Chun, Y. G., Park, B. O., and Yoon, K. H., “Synthesis of CuInSe2 and CuInGaSe2 nanoparticles by solvothermal route,” Mater. Sci. Forum, 273, 449(2004).Google Scholar
Ahn, S. J., Kim, K. H., Chun, Y. G., and Yoon, K. H., “Nucleation and growth of CIGS nanoparticles in low temperature colloidal process,” Thin Solid Films, 515, 4036(2007).CrossRefGoogle Scholar
Alberts, V. and Chenene, M. L., “Material properties of CIGS thin films prepared by the reaction of thermally evaporated compound materials in H2Se/Ar.” Semicond. Sci. Technol. 18, 870(2003).CrossRefGoogle Scholar
Castro, S. L., Bailey, S. G., Raffaelle, R. P., Banger, K. K., and Hepp, A. F., “Synthesis and characterization of colloidal CuInS2 nanoparticles from a molecular single-source precursor.” J. Phys. Chem. B, 108, 12429(2004).CrossRefGoogle Scholar