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The Synthesis of InP drom Indium Halides and Tris(Trimethylsilyl)Phosphine

Published online by Cambridge University Press:  25 February 2011

Matthew D. Healy
Affiliation:
Department of Chemistry, Harvard University, Cambridge, MA 02138
Paul E. Laibinis
Affiliation:
Department of Chemistry, Harvard University, Cambridge, MA 02138
Paul D. Stupik
Affiliation:
Department of Chemistry, Harvard University, Cambridge, MA 02138
Andrew R. Barron
Affiliation:
Department of Chemistry, Harvard University, Cambridge, MA 02138
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Abstract

InP has been prepared by the reaction of InX3 (X = Cl, Br, I) with P(SiMe3)3. The intermediates and product have been characterized by XPS, elemental analysis and X-ray powder diffraction.

Type
Research Article
Copyright
Copyright © Materials Research Society 1989

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References

REFERENCES

1. (a) Maury, F. and Constant, G., Polyhedron, 3, 581 (1984). (b) O.T. Beachley, Jr., J.P. Kopasz, H. Zhang, W.E. Hunter and J.L. Atwood, J. Organometal. Chem., 325, 69 (1987). (c). C.J. Carrano, A.H. Cowley, D.M. Giolanda, R.A. Jones, C.M. Nunn and J.M. Power, Inorg. Chem., 27, 2709 (1988).Google Scholar
2. Coates, G.E. and Graham, J., J. Chem. Soc., 1963, 233.Google Scholar
3. Arif, A.M., Benac, B.L., Cowley, A.H., Geertz, R., Jones, R.A., Kidd, K.B., Power, J.M. and Schwab, S.T., J. Chem. Soc., Chem. Commun., 1986, 1543.Google Scholar
4. Arif, A.M. and Barron, A.R., Polyhedron, in press.Google Scholar
5. Healy, M.D., Laibinis, P.E., Stupik, P.D., and Barron, A.R., J. Chem. Soc., Chem. Commun., in press.Google Scholar
6. Becker, G. and Holderich, W., Chem. Ber., 108, 2484, (1975).Google Scholar