Hostname: page-component-745bb68f8f-kw2vx Total loading time: 0 Render date: 2025-01-29T23:55:24.195Z Has data issue: false hasContentIssue false
  • English
  • Français

Synthesis of SrRuO3 by Sol-Gel Processing

Published online by Cambridge University Press:  15 February 2011

Y. Wu ,
S. Zamani  and
G. Z. Cao
Y. Wu
Affiliation:
University of Washington, Dept. of Materials Science and Engineering, Seattle, WA 98195
S. Zamani
Affiliation:
University of Washington, Dept. of Materials Science and Engineering, Seattle, WA 98195
G. Z. Cao
Affiliation:
University of Washington, Dept. of Materials Science and Engineering, Seattle, WA 98195
Get access

Abstract

Electronic conductive oxide SrRuO3has been synthesized by sol-gel processing. Various precursors were tested and four different processing methods were developed. Stable SrRuO3sols were obtained using these four processing methods with various precursors. It was found that partial hydrolysis of strontium precursors was required to achieve a cross-condensation of ruthenium and strontium, so as to obtain a single phase SrRuO3perovskite at relatively low temperatures. The stable sols were either poured into petri-dishes to form xerogels or dip-coated on substrates to form thin films. Single phase SrRuO3perovskite was obtained after heat-treatment at 800 °C or higher temperatures. TGA/DTA, XRD and SEM were applied to characterize sol-gel derived SrRuO3ceramic powders and films.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 548: Symposia EE – Solid State Ionics V , 1998 , 587
Copyright
Copyright © Materials Research Society 1999

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Eom, C. B., Dover, R. B. V., Phillips, J. M., Werder, D. J., Marshall, J. H., Chen, C. H., Cava, R. J., and Fleming, R. M., Appl. Phys. Lett. 63, p. 2,570 (1993).Google Scholar
2. Kim, Y. T., Appl. Phys. Lett. 70, p. 209 (1997).Google Scholar
3. Auciello, O., Kingon, A. I. and Krupanidhi, S. B., Mater. Res. Bull. 21, p. 25 (1996).Google Scholar
4. Bensch, W., Schmalle, H. W. and Reller, A., Solid State Ionics, 43, p. 171 (1990).Google Scholar
5. Char, K., Colclough, M. S., Geballe, T. H., and Myers, K. E., Appl. Phys. Lett., 62, 196 (1993).Google Scholar
6. Gausepohl, S.C., Lee, M., Rao, R. A., and Eom, C. B., Phys. Rev. B54, P. 8,996 (1996).Google Scholar
7. Klein, L., Dodge, J. S., Geballe, T. H., Kapitulnik, A., Marshall, A. F., Antognazza, L., and Char, K., Appl. Phys. Lett. 66, p.2,427 (1995).Google Scholar
8. Jia, Q. X., Chu, F., Adams, C. D., Wu, X. D., Hawley, M., Cho, J. H., Findikoglu, A. T., Foltyn, S. R., Smith, J.L., and Mitchell, T.E., J. Mater. Res. 11, p. 2,263 (1996).Google Scholar
9. Eom, C. B., Cava, R. J., Fleming, R. M., Phillips, J. M., Dover, R. B. van, Marshall, J. H., Hsu, J. W., Krajewski, J. J., and Peck, W. F. Jr., Science, 258, p. 1,766 (1992).Google Scholar
10. Jiang, J. C., Pan, X. Q., and Chen, C. L., Appl. Phys. Lett. 72, p. 909 (1998).Google Scholar
11. Brady, J. E., Holum, J. R., in Fundamentals of Chemistry with qualitative analysis (John Wiley & Sons, 1988) pp. 798.Google Scholar