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Published online by Cambridge University Press: 21 February 2011
Numerical solution of Fick's second law of diffusion demonstrated that the error introduced in the ANSI/ANS-16.1-1986 procedure, by assuming a zero surface concentration, varied from about 30% for a leachability index of 5 to about 0.1% for an index of 10. Waste forms typically have indexes of 7 or greater, implying errors of less than 5% with this assumption. The estimated leachability index differs from the actual value by less than 0.2 when the numerical solution is analyzed as input experimental data, except for a leachability index as low as 5 (essentially the value for water).