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Thermal and Electrical Properties of Li20-V205-TeO2 Glassy System

Published online by Cambridge University Press:  10 February 2011

E. Sanchez  and
C. A. Angell
E. Sanchez
Affiliation:
Department of Chemistry, Arizona State University, Tempe, AZ 85287-1604, USA
C. A. Angell
Affiliation:
Department of Chemistry, Arizona State University, Tempe, AZ 85287-1604, USA
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Abstract

Oxide glasses had receive a great deal of attention on the last couple of years because of their potentially high cationic transport. Interesting features have been found on Li20-V205-TeO2 glassy system. Such materials were prepared under open air at 800°C and traditional quenching. Glass formation was been found up to 45% alkali concentration on the V205-TeO2 binary system. Upon addition of Li20 the glass transition temperature lowered systematically up to values near 175°C. Structural correlation between glass transition and structure are made. Those materials show high promise as electrolytes for solid-state batteries applications.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 548: Symposia EE – Solid State Ionics V , 1998 , 461
Copyright
Copyright © Materials Research Society 1999

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References

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