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Use of Saccharides as Solid-state Precursors for the Synthesis of Carbon Nanotubes

Published online by Cambridge University Press:  01 February 2011

Gokce Kucukayan ,
Serim Kayacan ,
Beril Baykal  and
Erman Bengu
Gokce Kucukayan
Affiliation:
kgokce@bilkent.edu.tr, Bilkent University, Institute of Materials Science and Nanotechnology, Ankara, N/A, Turkey
Serim Kayacan
Affiliation:
serim@bilkent.edu.tr, Bilkent University, Institute of Materials Science and Nanotechnology, Ankara, N/A, Turkey
Beril Baykal
Affiliation:
bbaykal@ug.bilkent.edu.tr, Bilkent University, Chemistry, Department of Chemistry, Ankara, N/A, Turkey
Erman Bengu
Affiliation:
bengu@fen.bilkent.edu.tr, Bilkent University, Chemistry, Department of Chemistry, Ankara, N/A, Turkey
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Abstract

Saccharides, ranging from simple table sugar (sucrose) to lactulose were successfully used as solid-state precursors for the synthesis of multi-walled carbon nanotubes (MWCNT). Dehydrated saccharide residues mixed with catalyst powders were subjected to pyrolysis at high temperatures (up to 1300°C) under flowing Argon atmosphere. Pyrolysis products were investigated using TEM, SEM, Raman spectroscopy and EDS. Images taken using the S/TEM and bright field mode of TEM showed the presence of helical multi-walled carbon nanotube (H-MWCNT) and regular MWCNT formation. More than two or three catalyst particles were observed to be present inside the hollow core of some of the nanotubes synthesized, suggesting a high level of capillary activity inside the tubes during synthesis.

Keywords

Cnanostructurepyrolysis
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1081: Symposium P – Carbon Nanotubes and Related Low-Dimensional Materials , 2008 , 1081-P05-14
Copyright
Copyright © Materials Research Society 2008

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References

REFERENCES

1. Iijima, S., Nature 354, 56 (1991).Google Scholar
2. Wang, Y.Y., Tang, G.Y., Koeck, F.A.M., Brown, B., Garguilo, J.M., and Nemanich, R.J., Diamond and Related Materials 13, 1287 (2004).Google Scholar
3. Ajayan, P.M., Schadler, L.S., Giannaris, C., and Rubio, A., Adv. Mater. 12, 750 (2000).Google Scholar
4. Bethune, D. S., Klang, C. H., deVries, M. S., Gorman, G., Savoy, R., Vazquez, J., and Beyers, R., Nature 363, 605 (1993).Google Scholar
5. Scott, C. D., Arepalli, S., Nikolaev, P., and Smalley, R. E., Appl. Phys. A 72, 573 (2001).Google Scholar
6. Peigney, A., Coquay, P., Flahaut, E., R. Vandenberghe, E., Grave, E. De, and Laurent, C., J. Phys. Chem. B 105, 9699 (2001).Google Scholar
7. Lin, C.H., Lee, S.H., Hsu, C.M., and Kuo, C.T., Diamond and Related Materials 13, 2147 (2004).Google Scholar
8. Awasthi, K., Srivastava, A., and Srivastava, O., J. Nanosci. Nanotech. 5, 1616 (2005).Google Scholar
9. Demoncy, N., Stephan, O., Brun, N., Colliex, C., Loiseau, A., and Pascard, H., Eur. Phys. J. B 4, 147 (1998).Google Scholar
10. Mohlala, M. S., Liu, X.Y., Witcomb, M.J., and Coville, N.J., Appl. Organometal. Chem. 21, 275 (2007).Google Scholar
11. Katsuki, H., Matsunaga, K., Egashira, M., and Kawasumi, S., Carbon 19, 148 (1981).Google Scholar
12. Rodriguez, N. M., Kim, M. S., Fortin, F., Mochida, I. and Baker, R. T. K., Appl. Catal. A 148, 265 (1997).Google Scholar
13. Kiang, C. H., Dresselhaus, M. S., Beyers, R., and Bethune, D. S., Chem. Phys. Lett. 259, 41 (1996).Google Scholar
14. Huang, Q. and Gao, L., Nanotechnology 15, 1855 (2004).Google Scholar
15. Zhou, Z., Ci, L., Chen, X., Tang, D., Yan, X., Liu, D., Liang, Y. Yuan, H., Zhou, W., Wang, G., and Xie, S., Carbon 41, 337 (2003).Google Scholar
16. Hussain, A., Nanotechnology 4, 925 (2003).Google Scholar
17. Valles, C., Perez-Mendoza, M., Castell, P., Martinez, M. T., and Maser, W. K., Nanotechnology 17, 4292 (2006).Google Scholar
18. Wei, J., Zhu, H., Jia, Y., Shu, Q., Li, C., Wang, K., Wei, B., Zhu, Y., Wang, Z., Luo, J., Liu, W., and Wu, D., Carbon 45, 2152 (2007).Google Scholar
19. Wei, J., Jiang, B., Wu, D., and Wei, B., J. Phys. Chem. B 108, 8844 (2004).Google Scholar
20. Yu, J. S., Yoon, S. B. and Chai, G. S., Carbon 39, 1421 (2001).Google Scholar