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UV-Radiation Induced Color Centers in Optical Fibers

Published online by Cambridge University Press:  25 February 2011

J. Simpson ,
J. Ritger  and
F. DiMarcello
J. Simpson
Affiliation:
AT&T Bell Laboratories, Murray Hill, NJ 07974
J. Ritger
Affiliation:
AT&T Bell Laboratories, Norcross, GA 30071
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Abstract

Paramagnetic color centers have been observed in germanium silicate and germanium phosphosilicate multimode optical fiber exposed to broadband ultraviolet light (2–5 eV). These centers are characterized by an ESR and optical absorption similar to 1 meV and 100 keV radiation induced defects and show an apparent saturation as the UV dose approaches 100 J/cm2. The UV induced ESR spectra are not identical to that induced by 60Co radiation however, similar Ge(2) and Ge(3) germanium defect signatures are apparent. For both compositions these centers are characterized by a rapidly increasing loss from 1.0 to 0.5 µm with an additional broad absorption peak at 1.5 µm for the phosphorus containing cores. We suggest that the UV induced optical absorptions for both compositions in the short wavelength range are due in part to the Ge(2) germanium substitutional sites and expect that the 1.5 µm absorption is due to the P1 phosphorus oxygen vacancy.

Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 61: Symposium P – Defects in Glasses , 1985 , 333
Copyright
Copyright © Materials Research Society 1986

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References

1. Kiristianpoller, N., Nucl. Instr. and Methods in Phys. Res. Bl, 198 (1984).Google Scholar
2. Nicoletta, C. A. and Eubanks, A. G., Appl. Opt. 11, 1365 (1972).Google Scholar
3. Lange, S. and Turner, W. H., Appl. Opt. 12, 1733 (1973).Google Scholar
4. Stathis, J. H. and Kastner, , Phil. Mag. B 49, 357 (1984).Google Scholar
5. Blyler, L. L. Jr, DiMarcello, F. V., Simpson, J. R., Sigety, E. A., Hart, A. C., Foertmeyer, V. A., J. Non-cryst. Solids 38 and 39, 165 (1980).CrossRefGoogle Scholar
6. Stone, F. T. and Eichenbaum, B., J. Non-crys. Solids 38 and 39, 189 (1980).Google Scholar
7. Schwartz, R. N., Blair, G. R., Tangonan, G. L., Chmulittrat, W. and Kevan, L., J. Non-crys. Solids 38 and 39, 189 (1980).Google Scholar
8. Stathis, J. H. and Kastner, M. A., Phys. Rev. B 29, 7079 (1984).Google Scholar
9. Ilno, A., Tamura, T., Orimo, K., Kamiya, T. and Ogai, M., Proc. of European Conf. on Optical Communications, Venice Italy, 527 (1985).Google Scholar
10. Friebele, E. J. and Griscom, D. L., in Treatise on Material Science and Technology, Vol.17, Glass II, edited by Tomozawa, M. and Doremus, R. H. (Academic Press. New York, 1979), p. 257.Google Scholar
11. Friebele, E. J., Griscom, D. L. and Siegel, G. H. Jr, J. Appl. Phys. 45, 3424 (1974).Google Scholar
12. Kawazoe, H., J. Non-cryst Solids 71, 231 (1985).Google Scholar
13. Griscom, D. L., Friebele, E. J., Long, K. J. and Fleming, J. W., J. Appl. Phys. 54, 3743 (1983).Google Scholar
14. Firebele, E. J., private communication.Google Scholar
15. Friebele, E. J. and Griscom, D. L., private communication.Google Scholar