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Vanadium-Oxo Based Hybrid Organic-Inorganic Copolymers

Published online by Cambridge University Press:  10 February 2011

A. Campero ,
A. M. Soto ,
J. Maquet  and
C. Sanchez
A. Campero
Affiliation:
Departamento de Química, Universidad Autónoma Metropolitana (Iztapalapa), México DF 09340, México, acc35@xanum.uam.mx
A. M. Soto
Affiliation:
Departamento de Química, Universidad Autónoma Metropolitana (Iztapalapa), México DF 09340, México, acc35@xanum.uam.mx
J. Maquet
Affiliation:
Laboratoire de Chimie de la Matière Condensé-URA 1466, Université Pierre et Marie Curie, 4, place Jussieu, Paris, France
C. Sanchez
Affiliation:
Laboratoire de Chimie de la Matière Condensé-URA 1466, Université Pierre et Marie Curie, 4, place Jussieu, Paris, France
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Abstract

We describe the synthesis and characterization of hybrid organicinorganic copolymer materials formed by the reaction of the transition metal alkoxide VO(OAmt)3 with the chelating monomer ligand acetoacetoxyethylmethacrylate (AAEM). By the simultaneous induction of the organic and inorganic polymerization reactions, covalent bonds are formed between both types of interpenetrating components. The organic chelating moiety of AAEM is linked through its ß-diketo function to the vanadium-oxo species.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 435: Symposium V – Better Ceramics Through Chemistry VII , 1996 , 527
Copyright
Copyright © Materials Research Society 1996

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