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Vitrification of Simulated Intermediate-Level French and Russian Wastes in “Cold Crucible” Based Plant

Published online by Cambridge University Press:  15 February 2011

F. A. Lifanov
Affiliation:
SIA “Radon”, 7-th Rostovskii per. 2/14, Moscow, 119121 Russia
S. V. Stefanovsky
Affiliation:
SIA “Radon”, 7-th Rostovskii per. 2/14, Moscow, 119121 Russia
A. P. Kobelev
Affiliation:
SIA “Radon”, 7-th Rostovskii per. 2/14, Moscow, 119121 Russia
V. I. Kornev
Affiliation:
SIA “Radon”, 7-th Rostovskii per. 2/14, Moscow, 119121 Russia
A. E. Savkin
Affiliation:
SIA “Radon”, 7-th Rostovskii per. 2/14, Moscow, 119121 Russia
O. A. Knyazev
Affiliation:
SIA “Radon”, 7-th Rostovskii per. 2/14, Moscow, 119121 Russia
T. N. Lashchenova
Affiliation:
SIA “Radon”, 7-th Rostovskii per. 2/14, Moscow, 119121 Russia
S. Merlin
Affiliation:
SGN, Paris, France
P. Roux
Affiliation:
SGN, Paris, France
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Abstract

Comparative tests on SGN and Radon simulated ILW vitrification with a cold crucible based experimental plant were performed. The batch was fed as paste with 20 wt.% moisture. An operation conditions, the ability of the cold crucible to maintain the differential pressure during the operation, process variables, product properties, off-gas and condensate compositions, the effect of melt agitation on melter capacity and cesium loss have been determined. Melt viscosity and resistivity have been measured. Material structures were studied using infra-red spectroscopy and electron microscopy. Leach rates of sodium and potassium cations as well as Cs-137 have been measured. The behavior of sulfate and chloride ions in the vitrification process as well as their solubility in SGN and “Radon” glasses have been investigated.

Type
Research Article
Copyright
Copyright © Materials Research Society 1996

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