Hostname: page-component-78c5997874-t5tsf Total loading time: 0 Render date: 2024-11-10T05:49:32.718Z Has data issue: false hasContentIssue false

Waste Vitrification: Prediction of Acceptable Compositions in a Lime-Soda-Silica Glass-Forming System

Published online by Cambridge University Press:  03 September 2012

T M. Gilliam
Affiliation:
Oak Ridge National Laboratory, Oak Ridge, TN 37831, tmg@ornl.gov
T. M. Jantzen
Affiliation:
Westinghouse Savannah River Technology Center, Aiken, SC 29802
Get access

Abstract

A model is presented based upon calculated bridging oxygens which allows the prediction of the region of acceptable glass compositions for a lime-soda-silica glass-forming system containing mixed waste. The model can be used to guide glass formulation studies (e.g., treatability studies) or assess the applicability of vitrification to candidate waste streams.

Type
Research Article
Copyright
Copyright © Materials Research Society 1997

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Strategie Plan for the Treatment of Appendix B Wastes, DOE/OR-1083, Rev. 0, U.S. Department of Energy, February 12, 1993.Google Scholar
2. Jantzen, C. M., Hudson, W. D., Gilliam, T. M., Bleier, A., and Spence, R. D., “Vitrification Treatability Studies of Actual Waste Water Treatment Sludges,” in Waste Management '95 Proceedings, 1995.Google Scholar
3. Dean, J. A., ed., Lange's Handbook of Chemistry, 14th Ed., McGraw-Hill, Inc., New York, 1992.Google Scholar
4. Stevels, J. M., Glass Ind. 35, 69 (1954).Google Scholar
5. Trapp, H. J. L. and Stevels, J. M., Glastechn. Ber., 32, K, VI., 3252 (1959)Google Scholar
6. Gilliam, T. M., Jantzen, T. M., Bleier, A., Cooper, S. P., Mattus, C. H., McKeown, C. K., Roe, M. M., Spence, R. D., Szczygiel, T., and Trotter, D. R., Vitrification of Wastewater Treatment Sludge. Volume II: Crucible-Scale Formulation Development Studies with Actual West End Treatment Facility Sludge, ORNL/TM-13331, Oak Ridge National Laboratory, Oak Ridge, TN, 1996.Google Scholar
7. Levin, E. M., Robbins, C. R., and McMurdie, H. F., Phase Diagrams for Ceramists, The American Ceramic Society, 1964.Google Scholar
8. Jantzen, C. M., Pickett, J. B., and Ramsey, W. G., “Reactive Additive Stabilization Process for Hazardous and Mixed Waste Vitrification,” in Proceedings of the Second International Symposium on Mixed Waste, Baltimore, MD, edited by Moghissi, A. A., Blauvelt, R. K., Benda, G. A., and Rotermich, N. E., American Society of Mechanical Engineers, 1993, pp. 4.2.1–4.2.13.Google Scholar