Published online by Cambridge University Press: 26 February 2011
Infrared, photoconductivity, and photothermal deflection spectroscopy measurements have been used to probe the relationship between material quality and the amount of microstructure in glow discharge deposited a-SiC:H and a-SiGe:T films. We find that the microstructure is directly responsible for the decrease in photoconductivity observed in both alloys as a function of increased alloy content. The microstructure does this by causing a decrease in steepness of the Urbach tail, thus allowing for an increase in both carrier trapping at the wider band edges and carrier recombination at or near the band tails.