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New powder diffraction data of some derivatives of N-alkyl (aryl)-2,4-dichlorophenoxyacetamide—New potential pesticides

Published online by Cambridge University Press:  29 February 2012

E. Olszewska ,
S. Pikus  and
B. Tarasiuk
E. Olszewska
Affiliation:
Department of Crystallography, Faculty of Chemistry, Maria Curie Sklodowska University, Maria Curie-Sklodowska Sqr. 3, 20-031 Lublin, Poland
S. Pikus
Affiliation:
Department of Crystallography, Faculty of Chemistry, Maria Curie Sklodowska University, Maria Curie-Sklodowska Sqr. 3, 20-031 Lublin, Poland
B. Tarasiuk
Affiliation:
Department of Organic Chemistry, Faculty of Chemistry, Maria Curie Sklodowska University, Gliniana Str. 33, 20-614 Lublin, Poland
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Abstract

Four new derivatives of N-aryl-2,4-dichlorophenoxyacetamide, 2-(2,4-dichlorophenoxy)-N-(4-fluorophenyl)acetamide, N-(4-bromophenyl)-2-(2,4-dichlorophenoxy)acetamide, N-[4-chloro-3-(trifluoromethyl)phenyl]-2-(2,4-dichlorophenoxy)acetamide, and N-(3-chloro-4-fluorophenyl)-2-(2,4-dichlorophenoxy)acetamide, and two of N-alkyl-2,4-dichlorophenoxyacetamide, N-dodecyl-2,4-dichlorophenoxy-acetamide and 2-(2,4-dichlorophenoxy)-N-hexadecylacetamide, have been characterized by X-ray powder diffraction. These organic compounds are potential pesticides. Experimental 2θ peaks positions, relative peak intensities, values of d and Miller indices, and unit cell parameters are presented.

Keywords

X-ray powder diffractionpesticideN-aryl-24-dichlorophenoxyacetamideN-alkyl-2,4-dichlorophenoxyacetamide
Type
New Diffraction Data
Information
Powder Diffraction , Volume 23 , Issue 4 , December 2008 , pp. 338 - 349
Copyright
Copyright © Cambridge University Press 2008

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References

de Wolff, P. M. (1968). “A simplified criterion for the reliability of a powder pattern indexing,” J. Appl. Crystallogr.JACGAR10.1107/S002188986800508X 1, 108–113.CrossRefGoogle Scholar
Gruzdyev, G. S., Zinchenko, V. A., Kalinin, V. A., and Slovtsov, R. I. (1988). The Chemical Protection of Plants (Mir Publishers, Moscow), pp. 364–377.Google Scholar
Hutson, D. H. and Roberts, T. R. (Eds.) (1983). Progress in Pesticide Biochemistry and Toxicology (Wiley, New York), Vol. III, pp. 231–245.Google Scholar
Marciniak, H. and Diduszko, R. (1994). XRAYAN: Computer program for X-ray diffraction phase analyzes, version 2.90, Warsaw, Poland.Google Scholar
Melnikow, N. N. (1987). “Aryloxyalkylcarboxylic acids and their derivatives,” in Pesticide. Khimiya, Tekhnologiya i Prymienienie, edited by Nowozyw, K. W. (Khimiya, Moscow), pp. 222–248.Google Scholar
Podkościelny, W., Tarasiuk, B., and Zimińska, Z. (1994). “Synteza, struktura i fizykochemiczne oraz biologiczne właściwości pochodnych kwasu 2(2,4,5-trichloro-fenoksy)propionowego,” Przem. Chem.PRCHAB 73, 466–468.Google Scholar
Smith, G. S. and Snyder, R. L. (1979). “F N: A criterion for rating powder diffraction patterns and evaluating the reliability of powder-pattern indexing,” J. Appl. Crystallogr.JACGAR10.1107/S002188987901178X 12, 60–65.CrossRefGoogle Scholar
Tarasiuk, B. (2007). “Syntheses, structures and properties of halogenoanilides derivatives of dichlorophenoxyacetic acids,” Ann. Univ. Maria Curie Skłodowska, Sectio AA [Chemia] 62, 234–249.Google Scholar
Tarasiuk, B. and Podkościelny, W. (1995). “Synthesis, structure and physico-chemical and biological properties of selected 2-aryloxypropionate S-arylalkylisothiouronic,” Przem. Chem.PRCHAB 74, 250–251.Google Scholar
Tarasiuk, B., Podkościelny, W., Zimińska, Z., and Krawczyk, M. (2000). “1H-1,2,4-Triazoles derivatives of halogenphenoxyalkane acids with herbicidal activity,” Pestycydy 1–2, 5–15.Google Scholar
Werner, P.-E., Eriksson, L., and Westdahl, M. (1985). “TREOR, a semi-exhaustive trial-and-error powder indexing program for all symmetries,” J. Appl. Crystallogr.JACGAR10.1107/S0021889885010512 18, 367–370.CrossRefGoogle Scholar