Hostname: page-component-cd9895bd7-jkksz Total loading time: 0 Render date: 2024-12-26T09:16:59.455Z Has data issue: false hasContentIssue false
  • English
  • Français

Structure determination of a novel metal-organic compound synthesized from aluminum and 2,5-pyridinedicarboxylic acid

Published online by Cambridge University Press:  06 March 2012

Kenny Ståhl ,
Bastian Brink  and
Jonas Andersen
Kenny Ståhl*
Affiliation:
Department of Chemistry, Building 207, Technical University of Denmark, DK-2800 Kgs. Lyngby, Denmark
Bastian Brink
Affiliation:
Department of Chemistry, Building 207, Technical University of Denmark, DK-2800 Kgs. Lyngby, Denmark
Jonas Andersen
Affiliation:
Department of Chemistry, Building 207, Technical University of Denmark, DK-2800 Kgs. Lyngby, Denmark
*
a)Author to whom correspondence should be addressed. Electronic mail: kenny@kemi.dtu.dk
Get access Rights & Permissions [Opens in a new window]

Abstract

The structure of [Al2(pydc)2(μ2-OH)2(H2O)2]n(pydc = 2,5-pyridinedicarboxylate) was successfully determined from powder X-ray diffraction data. The compound crystallizes in the triclinic system (space group P -1) with a = 6.7813(1) Å, b = 7.4944(1) Å, c = 8.5013(1) Å, α = 95.256(1)°, β = 102.478(1)°, γ = 108.979(1)°. The structure consists of aluminum ions coordinating N and O in distorted octahedra, sharing an edge through two hydroxide ions. These dinuclear complexes are connected by pydc ions, which at one end coordinate by nitrogen and oxygen and only by oxygen at the other end. The pydc orientation is reversed in the neighboring pydc, forming double stranded chains interconnected by the aluminum dinuclear complexes in a ladder-like arrangement along [001].

Keywords

aluminum2,5-pyridinedicarboxylic acidhydrothermal synthesismetal-organic frameworkXRPD
Type
Technical Articles
Information
Powder Diffraction , Volume 26 , Supplement S1 , December 2011 , pp. S44 - S46
Copyright
Copyright © Cambridge University Press 2011

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Altomare, A., Burla, M. C., Cascarano, G., Giacovazzo, C., Guagliardi, A., Moliterni, A. G. G., and Polodori, G. (1995). “EXTRA: A program for extracting structure-factor amplitudes from powder diffraction data,” J. Appl. Crystallogr. 28, 842–846.10.1107/S0021889895005619CrossRefGoogle Scholar
Altomare, A., Cascarano, G., Giacovazzo, C., Burla, M. C., Polodori, G., and Camalli, G. (1994). “SIR92—A program for automatic solution of crystal structures by direct methods,” J. Appl. Crystallogr. 27, 435–436.10.1107/S002188989400021XGoogle Scholar
Férey, G. (2008). “Hybrid porous solids: Past, present, future,” Chem. Soc. Rev. 37, 191–214.10.1039/b618320bCrossRefGoogle ScholarPubMed
Han, Z. and Ma, Y. (2006). “Poly[di-μ2-aqua-μ-pyrazole-3,5-dicarboxylato-copper(II)],” Acta. Crystallogr. E 62, m2236–m2237.10.1107/S1600536806031795CrossRefGoogle Scholar
Howard, C. J. and Hill, R. J. (1986). A computer program for Rietveld analysis of fixed wavelength X-ray and neutron powder diffraction patterns, AAEC (now ANSTO) Report M112, Lucas Heights Research Laboratory, Australia.Google Scholar
King, P., Clérac, R., Anson, C. E., and Powell, A. K. (2004). “The building block approach to extended solids: 3,5-pyrazoledicarboxylate coordination compounds of increasing dimensionality,” Dalton Trans. 852–861.10.1039/b315067dCrossRefGoogle ScholarPubMed
Li, H., Eddaoudi, M., O’Keeffe, M., and Yaghi, O. M. (1999). “Design and synthesis of an exceptionally stable and highly porous metal-organic framework,” Nature (London) 402, 276–279.10.1038/46248CrossRefGoogle Scholar
Liang, Y., Hong, M., Cao, R., and Weng, J. (2001). “Hydrothermal synthesis and structure characterization of compound Zn(H2pydc)2(H2O) (pydc = pyridine-2,5-dicarboxylate),” Chinese J. Struct. Chem. 20, 455–458.Google Scholar
Loiseau, T., Serre, C., Huguenard, C., Fink, G., Taulelle, F., Henry, M., Bataille, T., and Férey, G. (2004). “A Rationale for the large breathing of the porous aluminum terephthalate (MIL-53) upon hydration,” Chem. Eur. J. 10, 1373–1382.10.1002/chem.v10:6CrossRefGoogle ScholarPubMed
See supplementary material at http://dx.doi.org/10.1154/1.3659288E-PODIE2-26-006104 for CrystallograpficInformation File (CIF)CrossRefGoogle Scholar
Visser, J. W. (1969). “A fully automatic program for finding the unit cell from powder data,” J. Appl. Crystallogr. 2, 89–95.10.1107/S0021889869006649CrossRefGoogle Scholar
Supplementary material: PDF

Ståhl et al supplementary material

Ståhl et al supplementary material

Download Ståhl et al supplementary material(PDF)
PDF 20.8 KB