Hostname: page-component-cd9895bd7-mkpzs Total loading time: 0 Render date: 2024-12-26T08:54:30.839Z Has data issue: false hasContentIssue false
  • English
  • Français

X-ray powder diffraction analysis of an organic material for nonlinear optics 3-methyl-4-methoxy-4′-nitrostilbene

Published online by Cambridge University Press:  10 January 2013

Zong-ming Jin ,
Zheng Jin  and
Fang Huang
Zong-ming Jin
Affiliation:
Central Laboratory, Suzhou University, 1 Shizi Street, Suzhou, 215006, People's Republic of China
Zheng Jin
Affiliation:
Suzhou Testing Institute of Technology, 5 Minzhi Road, Suzhou, 215006, People's Republic of China
Fang Huang
Affiliation:
Department of Chemistry, Suzhou University, 1 Shizi Street, Suzhou, 215006, People's Republic of China
Get access Rights & Permissions [Opens in a new window]

Abstract

An organic nonlinear optical material, 3-methyl-4-methoxy-4′-nitrostilbene (C16H15NO3), has been characterized by X-ray powder diffraction. Experimental values of 2θ corrected for systematic errors, relative peak intensities, values of d, and the Miller indices of 77 observed reflections with 2θ up to 82° are reported. The powder diffraction data have been evaluated, and the figures-of-merit are reported. The unit cell parameters least-squares refined from 30 non-overlapping peaks of the orthorhombic compound with a Aba2 space group are a=15.7882(3) Å, b=13.4892(4) Å, c=13.3940(2) Å, V=2852.5(4) Å3, Z=8, Dx=1.254 g/cm3. The powder diffraction results are in a agreement with those obtained from single-crystal structure data.

Type
Research Article
Information
Powder Diffraction , Volume 12 , Issue 3 , September 1997 , pp. 136 - 137
Copyright
Copyright © Cambridge University Press 1997

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Appleman, D. E. and Evans, H. T., Jr. (1973). “Indexing and Least-Squares Refinement of powder Diffraction Data,” Rep. PB 216188, U.S. Department of Commerce, National Technical Information Service, 5286 Port Royal Rd., Springfield, VA 22151.Google Scholar
Bierlein, J. D., Cheng, L. K., Wang, Y., and Tam, W. (1990). “Linear and nonlinear optical properties of 3-methyl-4-methoxy-4′-nitrostilbene single crystals,” Appl. Phys. Lett. 56(5), 423.CrossRefGoogle Scholar
de Wolff, P. M. (1968). “Powder Pattern Indexing,” J. Appl. Crystallogr. 1, 108.CrossRefGoogle Scholar
Smith, G. S. and Snyder, R. L. (1973). “F N: A Criterion for Rating Powder Diffraction Patterns and Evaluating the Reliability of Powder Pattern Indexing,” J. Appl. Crystallogr. 12, 60.Google Scholar
Werner, P. F. (1984). “TREOR, Trial and Error Program for Indexing of Unknown Powder Patterns,” University of Stockholm, S 106 91, Stockholm, Sweden.Google Scholar
Zong-ming, Jin, Zheng, Jin, and Xiang-yin, Zhou (1995). “X-Ray Powder Diffraction Analysis of a nonlinear Optical Material 3-nitro-4-hydroxy-4-bromobenzophenone,” Powder Diffr. 10(2), 117.Google Scholar