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X-ray powder diffraction data for cubic Sb3Nb3O13

Published online by Cambridge University Press:  10 January 2013

T. N. Blanton ,
C. L. Barnes  and
D. J. Eichorst
T. N. Blanton
Affiliation:
Analytical Technology Division, Eastman Kodak Company, Rochester, New York 14652-3712
C. L. Barnes
Affiliation:
Analytical Technology Division, Eastman Kodak Company, Rochester, New York 14652-3712
D. J. Eichorst
Affiliation:
Corporate Research Laboratories, Eastman Kodak Company, Rochester, New York 14650-2011
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Abstract

An Sb3Nb3O13 [Sb(III)2Sb(v)Nb(v)3O13] phase having a defect pyrochlore structure has been prepared by heating a sol–gel derived powder in oxygen. X-ray powder diffraction results indicate that Sb3Nb3O13 has a face-centered cubic structure, S.G. Fd3m(227), with a refined unit cell parameter a =10.4965(1) Å, calculated density Dx=4.893, four molecules per unit cell (Z), and a calculated figure of merit SS/FOM F30=92.4(0.009,38).

Keywords

antimony niobatesol-gelX-ray diffraction
Type
Research Article
Information
Powder Diffraction , Volume 8 , Issue 3 , September 1993 , pp. 188 - 190
Copyright
Copyright © Cambridge University Press 1993

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References

Appleman, D. E., and Evans, H. T. Jr., (1973). Rep. PB216188, U.S. Department of Commerce, National Technical Information Service, 5825 Port Royal Road, Springfield, VA 22151, USA.Google Scholar
Ayyub, P., Palkar, V. R., Multani, M. S., and Vijayaraghavan, R. (1987). “Structural, Dielectric, and Vibrational Properties of the Stibiotantalite (Sb1−xBix)NbO4 System for 0 <X< 1,” Ferroelectrics 76, 93–106.CrossRefGoogle Scholar
Gem Dugout, 1652 Princeton Drive, State College, PA 16803, USA.Google Scholar
Popolitov, V. I., Ivanova, L. A., Stephanovitch, S. Y., Chetchkin, V. V., Lobachev, A. N., and Venevtsev, Y. N. (1974). “Ferroelectric ABO4: Synthesis of Single Crystals and Ceramics; Dielectric and Nonlinear Optical Properties,” Ferroelectrics 8, 519–520.CrossRefGoogle Scholar
Powder Diffraction File, JCPDS-International Centre for Diffraction Data, Newtown Square Corporate Campus, 12 Campus Boulevard, Newtown Square, PA 19073-3273, USA.Google Scholar
Siemens-Allis (1991). D5000 V2.32 Software, 6300 Enterprise Lane, Madison, WI 53719, USA.Google Scholar
Stewart, D., Knop, O., Ayasse, C., and Woodhams, F. (1972). “Pyrochlores. VII. The Oxides of Antimony: An X-ray and Mossbauer Study,” Canad. J. Chem. 50, 690–700.CrossRefGoogle Scholar