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Cystamindi-ium tetrachlorocuprate [NH3(CH2)2SS(CH2)2NH3][CuCl4]: synthesis, crystal structure, and thermal decomposition

Published online by Cambridge University Press:  11 March 2015

D. Y. Leshok ,
N. N. Golovnev  and
S. D. Kirik
D. Y. Leshok
Affiliation:
Siberian Federal University, 660041, Krasnoyarsk, 79 Svobodny av., Russian Federation
N. N. Golovnev
Affiliation:
Siberian Federal University, 660041, Krasnoyarsk, 79 Svobodny av., Russian Federation
S. D. Kirik*
Affiliation:
Siberian Federal University, 660041, Krasnoyarsk, 79 Svobodny av., Russian Federation
*
a)Author to whom correspondence should be addressed. Electronic mail: Kiriksd@yandex.ru
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Abstract

The salt [NH3(CH2)2SS(CH2)2NH3][CuCl4] was obtained by crystallization after adding CuCl2 to cystamine (Cysta), solved in hydrochloric acid. The assumption of conserved disulfide connection (S–S) in the compound, made on the basis of infrared spectroscopy, is further supported by the crystal structure determined from X-ray powder diffraction data. The compound has an ionic structure. [CuCl4]2− and CystaH22+ ions package in the form of inorganic and organic layers in the cell, interconnected through the formation of hydrogen bonds via NH3-groups and chlorine atoms of the complex [CuCl4]2−. Inorganic layers are additionally stabilized in the parquet package of [CuCl4]2− ions which provides a Cu-distorted octahedral coordination. CystaH2[CuCl4] is stable in air up to 200 °C. Thermal decomposition occurs in several stages, accompanied by breaking of S–S bonds, releasing of the organic component and yielding CuO.

Keywords

copper dichloride (CuCl2)cystaminedisulfideX-ray powder crystal structure determinationthermal analysis
Type
Technical Articles
Information
Powder Diffraction , Volume 30 , Issue 2 , June 2015 , pp. 163 - 169
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Copyright
Copyright © International Centre for Diffraction Data 2015 

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References

Allegra, P., Amodeo, E., and Colombatto, S. (2002). “The ability of cystamine to bind DNA,” Amino Acids 22, 155–166.CrossRefGoogle ScholarPubMed
Allen, F. H. (2002). “The Cambridge Structural Database: a quarter of a million crystal structures and rising,” Acta Crystallogr. B 58, 380–388.CrossRefGoogle ScholarPubMed
Bharara, M. S., Bui, T. H., Parkin, S., and Atwood, D. A. (2005a). “Mercurophilic interaction in novel polynuclear Hg(II)-2-aminoethanethiolates,” Dalton Trans. 24, 3874–3880.CrossRefGoogle Scholar
Bharara, M. S., Parkin, S., and Atwood, D. A. (2005b). “Solution behavior of Hg(II)-cystamine by UV–Vis and 199Hg NMR,” Main Group Chem. 4, 217–225.CrossRefGoogle Scholar
Bi, W., Louvain, N., Mercier, N., Luc, J., and Sahraoui, B. (2007). “Type structure, which is composed of organic diammonium, triiodide and hexaiodobismuthate, varies according to different structures of incorporated cations,” Cryst. Eng. Commun. 9, 298–303.CrossRefGoogle Scholar
Bi, W., Louvain, N., Mercier, N., Luc, J., Rau, I., Kajzar, F., and Sahraoui, B. (2008). “A switchable NLO organic-inorganic compound based on conformationally chiral disulfide molecules and Bi(III)I-5 iodobismuthate networks,” Adv. Mater. 20, 1013–1017.CrossRefGoogle Scholar
Carrillo, D., Gouzerh, P., and Jeannin, Y. (1989). “Disulphide bond cleavage in the Nickel(II)-cystamine and copper(II)-cystamine systems. X-ray crystal structure of trans-[Ni(SCH2CH2NH2)2],” Polyhedron 8, 2837–2840.CrossRefGoogle Scholar
Eremin, A. V., Antonov, V. G., and Panina, N. S. (2009). “Coordination compounds of palladium and iron with oxygen-bridged ligands involved in the oxidation of thioamino acids,” Rossiiski. Khim. J. 53, 135–139.Google Scholar
Favre-Nicolin, V. and Černý, R. (2002). “FOX, ‘free objects for crystallography’: a modular approach to ab initio structure determination from powder diffraction,” J. Appl. Crystallogr. 35, 734–743.CrossRefGoogle Scholar
Foye, W. O. and Kaewchansilp, V. (1979). “Mercaptoalkylamine coordination compounds of platinum(II) and palladium(II) and their anticancer activity,” J. Pharm. Sci. 68, 1131–1135.CrossRefGoogle ScholarPubMed
Kennard, O. (1965). Cambridge Structural Database (Database) (University of Cambridge, Cambridge, UK).Google Scholar
Kim, C. H., Parkin, S., Bharara, M., and Atwood, D. (2002). “Linear coordination of Hg(II) by cysteamine,” Polyhedron 21, 225–228.CrossRefGoogle Scholar
Kirik, S. D. (1985). “Refinement of the crystal structures along the powder pattern profile by using rigid structural constraints,” Kristallographia 30, 185–187.Google Scholar
Kirik, S. D., Borisov, S. V., and Fedorov, V. E. (1981). “Program for crystal structure refinement using X-ray powder pattern,” Zh. Strukt. Khim. 22, 131–135.Google Scholar
Louvain, N., Bi, W., and Mercier, N. (2007). “PbnI4n + 2(2n + 2)− Ribbons (n = 3, 5) as dimensional reductions of 2D perovskite layers in cystamine cation based hybrids, also incorporating iodine molecules or reversible guest water molecules,” Dalton Trans. 9, 965–970.CrossRefGoogle Scholar
Louvain, N., Mercier, N., and Kurmoo, M. (2008). “Cu–I–Br oligomers and polymers involving Cu–S(cystamine) bonds,” Eur. J. Inorg. Chem. 10, 1654–1660.CrossRefGoogle Scholar
Mark, H. F., Othmer, D. F., Overberger, C. G., and Seaborg, G. T. (1982). Kirk-Othmer Encyclopedia of Chemical Technology (Wiley, New York), 3rd ed., Vol. 19, p. 801.Google Scholar
Markello, T. C., Bernardini, I. M., and Gahl, W. A. (1993). “Improved renal function in children with cystinosis treated with cysteamine,” Engl. J. Med. 328, 1157–1162.CrossRefGoogle ScholarPubMed
Pavani, K., Upreti, S., and Ramanan, A. (2006). “Two new polyoxovanadate clusters templated through cysteamine,” J. Chem. Sci. 118, 159–164.CrossRefGoogle Scholar
Rodriguez-Carvajal, J. (2009). FullProf, version 4.06 (Computer Software), IUCr Software.Google Scholar
Shaw, C. F., Stillman, M. J., and Suzuki, K. T. (1991). Metallothioneins: Synthesis, Structure and Properties of Metallothioneins, Phytochelatins and Metal-Thiolate Complexes (VCH Publishers, New York), pp. 1–13.Google Scholar
Sheludyakova, L. A. and Basova, T. V. (2002). “Hexachlorocuprate (II) anion: the vibrational spectra and structure,” J. Struct. Khim. 43, 629–633.Google Scholar
Siemens (1989). XP. Molecular Graphics Program, version 4.0 (Computer Software), Siemens Analytical X-ray Instruments Inc., Madison, Wisconsin, USA.Google Scholar
Solovyov, L. A. and Kirik, S. D. (1993). “Application of simulated annealing approach in powder crystal structure analysis,” Mater. Sci. Forum 133–136.Google Scholar
Steele, R. A. and Opella, S. J. (1997). “Structures of the reduced and mercury-bound forms of MerP, the periplasmic protein from the bacterial mercury detoxification system,” Biochemistry 36, 6885–6895.CrossRefGoogle ScholarPubMed
Visser, J. W. (1969). “A fully automatic program for finding the unit cell from powder data,” J. Appl. Crystallogr. 2, 89–95.CrossRefGoogle Scholar
Wilson, J. R., Leang, C., Morby, A. P., Hobman, J. L., and Brown, N. L. (2000). “MerF is a mercury transport protein: different structures but a common mechanism for mercuric ion transporters?” FEBS Lett. 472, 78–82.CrossRefGoogle ScholarPubMed
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