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Equations for quantifying Fe and K within the illite structure using X-ray powder diffraction

Published online by Cambridge University Press:  06 March 2012

Il Mo Kang ,
Hi-Soo Moon ,
Yungoo Song  and
Myung Hun Kim
Il Mo Kang
Affiliation:
Department of Earth System Sciences, Yonsei University, 134, Sinchon-dong, Seodaemunku, Seoul, 120-749, Korea
Hi-Soo Moon*
Affiliation:
Department of Earth System Sciences, Yonsei University, 134, Sinchon-dong, Seodaemunku, Seoul, 120-749, Korea
Yungoo Song
Affiliation:
Department of Earth System Sciences, Yonsei University, 134, Sinchon-dong, Seodaemunku, Seoul, 120-749, Korea
Myung Hun Kim
Affiliation:
Department of Chemistry, Yonsei University, 134, Sinchon-dong, Seodaemunku, Seoul, 120-749, Korea
*
a)Author to whom correspondence should be addressed. Electronic mail: hsmoon@yonsei.ac.kr
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Abstract

This study was performed to suggest convenient equations for quantifying Fe and K within the illite structure using relative intensities for the illite basal reflections. The 002/005 and 003/005 ratios were available for Fe and K quantifications, and equations could be derived as the following: CFe=(ln I002/005−1.807 ln I003/005+1.29)/(1.241 ln I003/005−3.843), CK=−(ln I002/005+0.121 ln I003/005−2.592)/(1.308 ln I003/005+1.984). The equations may obtain Fe and K contents within ca. ±0.05 atoms per half-unit cell, if incident radiation loss is minimized and basal reflection modification caused by expandable layers is eliminated. © 2004 International Centre for Diffraction Data.

Type
Technical Articles
Information
Powder Diffraction , Volume 19 , Issue 3 , September 2004 , pp. 247 - 248
Copyright
Copyright © Cambridge University Press 2004

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References

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