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Mechanochemical synthesis of two-dimensional metal-organic frameworks

Published online by Cambridge University Press:  11 April 2019

Omar Barreda ,
Gregory R. Lorzing  and
Eric D. Bloch
Omar Barreda
Affiliation:
Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716
Gregory R. Lorzing
Affiliation:
Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716
Eric D. Bloch*
Affiliation:
Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716
*
a)Author to whom correspondence should be addressed. Electronic mail: edb@udel.edu
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Abstract

Powder X-ray diffraction was used to monitor the solvent-free synthesis of two-dimensional (2D) metal–organic frameworks (MOFs) via mechanochemical methods. For four isophthalic acid-based, alkoxide-functionalized organic ligands, optimal milling times were found to vary from 12 to 48 min. This work confirms that mechanochemical synthesis routes can be utilized to afford highly-crystalline, 2D MOFs.

Keywords

metal–organic frameworksmechanochemistry
Type
Technical Article
Information
Powder Diffraction , Volume 34 , Issue 2 , June 2019 , pp. 119 - 123
Copyright
Copyright © International Centre for Diffraction Data 2019 

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