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Powder diffraction data for the new aliphatic-aromatic thiodiols

Published online by Cambridge University Press:  06 March 2012

S. Pikus ,
E. Olszewska ,
W. Podkościelny ,
M. Rogulska  and
A. Kultys
S. Pikus*
Affiliation:
Department of Crystallography, Faculty of Chemistry, Maria Curie Sklodowska University, Pl. Marii Curie-Sklodowskiej 3, 20-031 Lublin, Poland
E. Olszewska
Affiliation:
Department of Crystallography, Faculty of Chemistry, Maria Curie Sklodowska University, Pl. Marii Curie-Sklodowskiej 3, 20-031 Lublin, Poland
W. Podkościelny
Affiliation:
Department of Organic Chemistry and Technology, Faculty of Chemistry, Maria Curie Sklodowska University, ul. Gliniana 33, 20-614 Lublin, Poland
M. Rogulska
Affiliation:
Department of Organic Chemistry and Technology, Faculty of Chemistry, Maria Curie Sklodowska University, ul. Gliniana 33, 20-614 Lublin, Poland
A. Kultys
Affiliation:
Department of Organic Chemistry and Technology, Faculty of Chemistry, Maria Curie Sklodowska University, ul. Gliniana 33, 20-614 Lublin, Poland
*
a)Electronic mail: stanpik@hermes.umcs.lublin.pl
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Abstract

Five new aliphatic-aromatic thiodiols: 1,2-bis[4-(2′-hydroxyethylthio)phenyl]ethane (C18H22O2S2), 1,2-bis[4-(3′-hydroxypropylthio)phenyl]ethane (C20H26O2S2), 1,2-bis[4-(6′-hydroxyhexylthio)phenyl]ethane (C26H38O2S2), 1,2-bis[4-(10′-hydroxydecylthio)phenyl]ethane (C34H54O2S2), 1,2-bis[4-(11′-hydroxyundecylthio)phenyl]ethane (C36H58O2S2) have been characterized by X-ray powder diffraction. These thiodiols can be used for synthesis of thermoplastic nonsegmented polyurethanes. Experimental 2θ peaks positions, relative peak intensities, values of d and Miller indices as well as unit cell parameters are reported.

Type
New Diffraction Data
Information
Powder Diffraction , Volume 18 , Issue 3 , September 2003 , pp. 240 - 243
Copyright
Copyright © Cambridge University Press 2005

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References

Ilavsky´, M., Bouchal, K., Valentová, H., Lednicky´, F., Sikora, A., and Baldria, J. (1998). “Molecular order and dynamic mechanical behavior of polyurethanes based on liquid crystalline diol,” J. Macromol. Sci., Phys. JMAPBR B37, 645–666. joh, JMAPBR CrossRefGoogle Scholar
Kultys, A.and Pikus, S. (2001). “Polyurethanes containing sulfur. III. New thermoplastic HDI-based segmented polyurethanes with diphenylmethane unit in their structure,” J. Polym. Sci., Part A: Polym. Chem. JPACEC 39, 1733–1742. poy, JPACEC CrossRefGoogle Scholar
Kultys, A., Podkościelny, W., and Majewski, W. (2000). “Polyurethanes containing sulfur. II. New thermoplastic nonsegmented polyurethanes with diphenylmethane unit in their structure,” J. Polym. Sci., Part A: Polym. Chem. JPACEC 38, 1767–1773. poy, JPACEC 3.0.CO;2-G>CrossRefGoogle Scholar
Kultys, A., Podkościelny, W., and Pikus, S. (1999). “Polyurethanes containing sulfur. I. New thermoplastic polyurethanes with benzophenone unit in their structure,” J. Polym. Sci., Part A: Polym. Chem. JPACEC 37, 4140–4150. poy, JPACEC 3.0.CO;2-K>CrossRefGoogle Scholar
Pikus, S. (2000). PDF 50–2286.Google Scholar
Podkościelny, W., Rogulska, M., Kultys, A., and Poz´dzik, E. (unpublished).Google Scholar
Smith, G. S., and Snyder, R. L. (1979). “FN: Criterion for rating power diffraction patterns and evaluating the reliability of powder-pattern indexing,” J. Appl. Crystallogr. JACGAR 12, 60–65. acr, JACGAR CrossRefGoogle Scholar
Valentová, H., Bouchal, K., Nedbal, J., and Ilavsky´, M. (1999). “Gelation and mechanical behavior of liquid crystalline networks,” J. Macromol. Sci., Phys. JMAPBR B38, 51–66. joh, JMAPBR CrossRefGoogle Scholar
Wdowicka, D., Podkościelny, W., and Kultys, A.(2000). “Polyurethanes (III): Polyaddition products of 4,4′-bis(2-hydroxyethylenetio)diphenyl ether and 2,4-tolylene diisocyanate,” Iran. Polym. J. 9, 97–103.Google Scholar
Wdowicka, D., Podkościelny, W., and Maziarczyk, H.(1997). “Polyurethanes (II): Products of polyaddition of bis(4-hydroxyethylenethio)diphenyl ether with 1,6-hexane diisocyanate,” Iran. Polym. J. 6, 253–260.Google Scholar
Werner, P. F. (1984). “TREOR, Trial and Error Program for Indexing of Unknown Powder Patterns,” University of Stockholm, S 106 91, Stockholm, Sweden.Google Scholar
Wolff, P. M. (1968). “A simplified criterion for the reliability of a powder pattern indexing,” J. Appl. Crystallogr. JACGAR 1, 108–113. acr, JACGAR CrossRefGoogle Scholar