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Powder diffraction data of novel complexes CdX2-2(NH2-PhY), part I

Published online by Cambridge University Press:  29 February 2012

Anna Dobija ,
Alicja Rafalska-Łasocha  and
Wiesław Łasocha
Anna Dobija
Affiliation:
Institute of Catalysis and Surface Chemistry, PAS, ul. Niezapominajek 8, 30-239 Krakow, Poland
Alicja Rafalska-Łasocha
Affiliation:
Faculty of Chemistry, Jagiellonian University, ul. Ingardena 3, 30-060 Krakow, Poland
Wiesław Łasocha*
Affiliation:
Institute of Catalysis and Surface Chemistry, PAS, ul. Niezapominajek 8, 30-239 Krakow, Polandand Faculty of Chemistry, Jagiellonian University, ul. Ingardena 3, 30-060 Krakow, Poland
*
a)Author to whom correspondence should be addressed; Electronic mail: lasocha@chemia.uj.edu.pl
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Abstract

Four new compounds with general formula CdI2-2(NH2-PhX) (Ph represents phenyl radical; X represents Cl or H atoms) were obtained and characterized. Two of them, bisaniline diiodidecadmium(II) — CdI2⋅2[NH2–C6H5] {1} and bis(2-chloroaniline) diiodidecadmium(II) — CdI2⋅2[NH2–C6H4Cl] {2}, crystallize in monoclinic system, whereas another two, bis(3-chloroaniline) diiodidecadmium(II) — CdI2⋅2[NH2–C6H4Cl]{3} and bis(4-chloroaniline) diiodidecadmium(II) hemi(4-chloroanilate) — CdI2⋅2[NH2–C6H4Cl]½[NH2–C6H4Cl] {4}, crystallize in triclinic system. The investigated compounds, from chemical point of view, are similar to the so-called cisplatin—a compound used as a chemotherapy drug to treat many types of cancers. Their syntheses and results of X-ray powder diffraction studies at room and elevated temperatures are described in this paper.

Keywords

X-ray powder diffractionhigh-temperature X-ray diffractionindexing of powder pattern
Type
New Diffraction Data
Information
Powder Diffraction , Volume 25 , Issue 4 , December 2010 , pp. 359 - 367
Copyright
Copyright © Cambridge University Press 2010

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