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Powder diffraction study of some mixed ligand complexes of Mn(II), Ni(II), Cu(II), Zn(II), and Cd(II)

Published online by Cambridge University Press:  05 March 2012

Ranjana Ghose  and
Rajesh Kumar
Ranjana Ghose*
Affiliation:
Department of Applied Chemistry, Institute of Technology, Banaras Hindu University, Varanasi, Uttar Pradesh 221005, India
Rajesh Kumar
Affiliation:
Department of Applied Chemistry, Institute of Technology, Banaras Hindu University, Varanasi, Uttar Pradesh 221005, India
*
a)Author to whom correspondence should be addressed. Electronic mail: rghose.apc@itbhu.ac.in
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Abstract

The mixed ligand complexes of manganese(II), nickel(II), copper(II), zinc(II), and cadmium(II) involving aspartic acid and benzoic acid have been synthesized. The complexes were studied by various spectroscopic techniques such as infrared, electronic, X-ray diffraction, and magnetic measurements. The complexes were found to have octahedral geometry. The X-ray powder diffraction results show that the crystal systems of Mn(II)-Asp-Ben complex are hexagonal, and Ni(II)-Asp-Ben, Cu(II)-Asp-Ben, Zn(II)-Asp-Ben, and Cd(II)-Asp-Ben complexes are found to be triclinic. The value of unit-cell parameters and XRD data for the five mixed ligand complexes are reported.

Keywords

aspartic acidbenzoic acidmixed ligand complexes
Type
New Diffraction Data
Information
Powder Diffraction , Volume 26 , Issue 1 , March 2011 , pp. 82 - 87
Copyright
Copyright © Cambridge University Press 2011

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