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Structural and Raman spectroscopic studies of the two M0.50SbFe(PO4)3 (M = Mg, Ni) NASICON phases

Published online by Cambridge University Press:  02 May 2017

Abderrahim Aatiq ,
Asmaa Marchoud ,
Hajar Bellefqih  and
My Rachid Tigha
Abderrahim Aatiq*
Affiliation:
Département de Chimie, Laboratoire de Physico-Chimie des Matériaux Appliqués, Université Hassan II de Casablanca, Faculté des Sciences Ben M'Sik, Avenue Idriss El harti, B.P. 7955, Casablanca, Morocco
Asmaa Marchoud
Affiliation:
Département de Chimie, Laboratoire de Physico-Chimie des Matériaux Appliqués, Université Hassan II de Casablanca, Faculté des Sciences Ben M'Sik, Avenue Idriss El harti, B.P. 7955, Casablanca, Morocco
Hajar Bellefqih
Affiliation:
Département de Chimie, Laboratoire de Physico-Chimie des Matériaux Appliqués, Université Hassan II de Casablanca, Faculté des Sciences Ben M'Sik, Avenue Idriss El harti, B.P. 7955, Casablanca, Morocco
My Rachid Tigha
Affiliation:
Département de Chimie, Laboratoire de Physico-Chimie des Matériaux Appliqués, Université Hassan II de Casablanca, Faculté des Sciences Ben M'Sik, Avenue Idriss El harti, B.P. 7955, Casablanca, Morocco
*
a)Author to whom correspondence should be addressed. Electronic mail: a_aatiq@yahoo.fr
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Abstract

Structures of the two M0.50SbFe(PO4)3 (M = Mg, Ni) phases, abbreviated as [Mg0.50] and [Ni0.50], were determined at room temperature from X-ray diffraction (XRD) powder data using the Rietveld analysis. Both compounds belong to the NASICON structural family. XRD patterns of [Mg0.50] and [Ni0.50] phases were easily indexed with a primitive hexagonal unit cell [P$\overline 3 $ space group, Z = 6] similar to that already obtained for La0.33Zr2(PO4)3. Obtained unit cells parameters are [a = 8.3443(1) Å, c = 22.3629(1) Å], and [a = 8.3384(1), c = 22.3456(1) Å], respectively, for [Mg0.50] and [Ni0.50] phosphates. In both samples, the [Sb(Fe)(PO4)3]− NASICON framework is preserved and a partially-ordered distribution of Sb5+ and Fe3+ ions is observed. Raman spectroscopic study was used to obtain further structural information about the nature of bonding in [Mg0.50] and [Ni0.50] phases.

Keywords

iron and antimony phosphateNASICON structureRaman spectroscopyRietveld analysis
Type
Technical Articles
Information
Powder Diffraction , Volume 32 , Supplement S1 , September 2017 , pp. S40 - S51
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Copyright
Copyright © International Centre for Diffraction Data 2017 

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