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Synthesis and X-ray characterization of Li(1−2x)NixTiO(PO4) (0≤x≤0.50)

Published online by Cambridge University Press:  05 March 2012

B. Manoun ,
A. El Jazouli ,
P. Gravereau  and
J. P. Chaminade
B. Manoun*
Affiliation:
Laboratoire de Chimie des Matériaux Solides, Faculté des Sciences Ben M’Sik Boulevard Idriss El Harti, Sidi Othman B.P. 7955 Casablanca, Morocco
A. El Jazouli
Affiliation:
Laboratoire de Chimie des Matériaux Solides, Faculté des Sciences Ben M’Sik Boulevard Idriss El Harti, Sidi Othman B.P. 7955 Casablanca, Morocco
P. Gravereau
Affiliation:
Institut de Chimie de la Matière Condensée de Bordeaux, 87, Av. du Dr. Schweitzer 33608 Pessac cedex, France
J. P. Chaminade
Affiliation:
Institut de Chimie de la Matière Condensée de Bordeaux, 87, Av. du Dr. Schweitzer 33608 Pessac cedex, France
*
a)Author to whom correspondence should be addressed; electronic mail: manounb@fiu.edu. Current address: Center for the Study of Matter at Extreme Conditions, U.P., VH-140, Miami, Florida 33199.
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Abstract

Li(1−2x)NixTiO(PO4) oxyphosphate powders were prepared from dilute solutions of NiCl2⋅6H2O, Li2CO3, (NH4)2HPO4, and TiCl4 in ethanol. The final temperature was 850 °C. Li(1−2x)NixTiO(PO4) oxyphosphates with 0≤x≤0.10 crystallize in the orthorhombic system with space group Pnma, while those with 0.10<x≤0.25 crystallize in the monoclinic system with space group P21/c.

Keywords

oxyphosphatesX-ray diffractionLi(1−2x)NixTiO(PO4)
Type
Technical Articles
Information
Powder Diffraction , Volume 18 , Issue 4 , December 2003 , pp. 301 - 305
Copyright
Copyright © Cambridge University Press 2003

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References

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