Hostname: page-component-cd9895bd7-gvvz8 Total loading time: 0 Render date: 2024-12-26T08:22:07.380Z Has data issue: false hasContentIssue false

X-ray powder diffraction data of hauyne with incommensurate modulated structure from volcanic rocks of Laacher Lake, Germany

Published online by Cambridge University Press:  10 January 2013

A. N. Sapozhnikov
Affiliation:
Institute of Geochemistry, Russian Academy of Sciences, Siberian Branch Irkutsk, 664033, Russia
V. G. Ivanov
Affiliation:
Institute of Geochemistry, Russian Academy of Sciences, Siberian Branch Irkutsk, 664033, Russia
L. F. Piskunova
Affiliation:
Institute of Geochemistry, Russian Academy of Sciences, Siberian Branch Irkutsk, 664033, Russia
E. K. Vasil'ev
Affiliation:
Institute of the Earth's Crust, Russian Academy of Sciences, Siberian Branch, Irkutsk, 664033, Russia

Abstract

Methods of the structure analysis were used to determine the incommensurate structure modulation in a sample of hauyne from Laacher Lake, Germany. The modulation parameter n=0.145, determined using single-crystal patterns, was refined using powder data. An indexing technique for additional reflections (satellites) using a parameter subcell and Miller index main reflections was suggested. Crystallographic characteristics of the hauyne of Laacher Lake are compared with that of hauyne from Sacrafano (Italy) and with lazurtes from Baikal, Pamir, and Afghanistan. We found that the crystal structure modulation can serve as a source of paragenesis information on sulphate bearing sodalte group minerals.

Type
Research Article
Copyright
Copyright © Cambridge University Press 1997

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Blaise, J., and Cesbron, F. (1966). Donnees mineralogiques at petrographiques sur le gisement de lapis-lazuli de Sar-e-Sang, Hndou-Kouch, Afghanistan,” Bull. Soc. Franc. Miner. Cryst. 89, 333343.Google Scholar
Burragato, F., Maras, A., and Rossi, A. (1987). “The sodalite group minerals in the volcanic areas of Latium,” N. Jb. Miner. Mh. H. 10, 433–445.Google Scholar
Buseck, P. R., and Cowley, J. M. (1983). “Modulated and intergrowth structures in minerals and electron microprobe methods for their study,” Am. Mineral. 68, 1840.Google Scholar
Deer, W. A., Howie, R. A., and Zussman, J. (1963). Rock-Forming Minerals. Vol. 4. Framework Silicates (Longmans, London), p. 482.Google Scholar
Hassan, I., and Buseck, P. R. (1989a). “Incommensurate-modulated structure of nosean, a sodalite group mineral,” Am. Mineral. 74, 394410.Google Scholar
Hassan, I., and Buseck, P. R. (1986b). “Cluster ordering and antiphase domain boundaries in hauyne,” Can. Mineral. 27, 173–80.Google Scholar
Hassan, I., and Grundy, H. D. (1989). “The structure of nosean, ideally Na8(Al6Si6O24)SO4.H2O,” Can. Mineral. 27, 165–172.Google Scholar
Ivanov, V. G., and Sapozhnikov, A. N. (1985). Lazurites of USSR (Nauka, Novosibirsk), p. 172 (in Russian).Google Scholar
Koto, K., Nakayama, Y., Morimoto, N., and Sadanaga, R. (1977). “Superlattice reflections and lattice images of hauyne,” Miner. Soc. Japan Annual Meeting, Abstr. B14 (in Japanese).Google Scholar
PDF 37-473 (1987). Powder Diffraction File (JCPDS, ICDD).Google Scholar
Saalfeld, H. (1961). “Structurbesonderheiten des Hauyngitter,” Z. Kristallogr. 115, 132140.CrossRefGoogle Scholar
Sapozhnikov, A. N. (1990). “Indexing of extra reflections on lazurite X-ray diffraction patterns in connection with modulation study of its structure,” Zap. Vseros. Miner. Obshch. 119(1), 110–116 (in Russian).Google Scholar
Sapozhnikov, A. N., Ivanov, V. G., Levitsky, V. I., and Piskunova, L. F. (1993). “Structure-mineralogical features of Southwest Pamir lazurite,” Zap. Vseros. Miner. Obshch. 122(1), 108–115 (in Russian).Google Scholar
Sapozhnikov, A. N., Medvedev A. Ya., Ivanov, V. G., Tauson, V. L., Matveeva, L. N. (1994). “On behaviour of modulated structure of Baikal lazurite by a high temperature annealing,” Zap. Vseros. Mineral. Obshch. 123(2), 82–88 (in Russian).Google Scholar
Sapozhnikov, A. N., Vasil’ev, E. K., and Bayliss, P. (1992). “On indexing X-ray diffraction powder patterns of cubic lazurites with incommensurate-modulated structure,” Powder Diffr. 7, 134136.CrossRefGoogle Scholar
Taylor, D. (1967). “The sodalite group minerals,” Contrib. Mineral. Petrol. 16, 172–188.CrossRefGoogle Scholar
Tsuchiya, N. (1984). “The study on the superstructure of hauyne,” thesis, The University of Tokyo.Google Scholar
Tsuchiya, N., and Takeuchi, Y. (1985). “Fine texture of Hauyne having a modulated structure,” Z. Kristallogr. 173, 273281.CrossRefGoogle Scholar